The reagent Et2AlX/CH2N2 in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

被引：0
|
作者：
I. R. Ramazanov
A. V. Yaroslavova
N. R. Yaubasarov
E. N. Gil’manova
U. M. Dzhemilev
机构：
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源：
Russian Chemical Bulletin | 2019年 / 68卷
关键词：
organoaluminum compounds; diazomethane; aluminum carbenoids; cyclopropanation;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A transition-metal-free method of cyclopropanation of sterically hindered olefins, substituted allylic alcohols, allylamines, and vinyl silyl ethers was developed using diazomethane in the presence of organic aluminum halides.
引用
收藏
页码：1869 / 1873
页数：4
相关论文
共 50 条
  • [21] Actions of Bisnucleophiles on (E)-3-[3-(2-Hydroxyaryl)-3-oxoprop-1-en-1-yl]chromones: Versatile Transformations into Oxygen- and Nitrogen-Containing Heterocycles
    Hassaine, Ridha
    Talhi, Oualid
    Taibi, Nadia
    Almeida Paz, Filipe A.
    Bensaid, Okkacha
    Bachari, Khaldoun
    Silva, Artur M. S.
    SYNLETT, 2016, 27 (03) : 465 - 470
  • [22] High-k properties of atomic-layer-deposited HfO2 films using a nitrogen-containing Hf[N(CH3)2]4 precursor and H2O oxidant
    Cho, M
    Park, HB
    Park, J
    Lee, SW
    Hwang, CS
    Jang, GH
    Jeong, J
    APPLIED PHYSICS LETTERS, 2003, 83 (26) : 5503 - 5505
  • [23] VIBRATION-SPECTRA AND STRUCTURE OF ALUMINUM BOROHYDRIDE COMPOUNDS WITH NITROGEN-CONTAINING LIGANDS AL(BH4)3.L (WHERE L-NH3,NH2CH3,NH(CH3)2,N(CH3)3)
    SEMENENKO, KN
    SHILKIN, SP
    POLYAKOVA, VB
    ZHURNAL NEORGANICHESKOI KHIMII, 1978, 23 (02): : 352 - 357
  • [24] NITROGEN-CONTAINING ORGANOSILICON COMPOUNDS .49. SYNTHESIS AND INSECTOREPELLENT PROPERTIES OF SI-SUBSTITUTED (ORGANYLAMINOMETHYL)SILANE OF SERIES (CH3)N (RO)3-N SICH2NR'R''
    LUKEVITS, E
    DREMOVA, VP
    SIMCHENKO, LI
    VORONKOV, MT
    KHIMIKO-FARMATSEVTICHESKII ZHURNAL, 1974, 8 (10): : 29 - 32
  • [25] CRYSTAL STUDIES OF HETEROCYCLIC-COMPOUNDS CONTAINING ONE OXYGEN AND 2 NITROGEN-ATOMS .2. N,N'-DITOSYLTETRAHYDRODIBENZO[B,H][1,4,7]OXADIAZONINE
    STEPIEN, A
    WAJSMAN, E
    GRABOWSKI, MJ
    GLINKA, R
    PERRIN, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2164 - 2165
  • [26] Calculation of 15N NMR Chemical Shifts in a Diversity of Nitrogen-Containing Compounds Using Composite Method Approximation at the DFT, MP2, and CCSD Levels
    Semenov, Valentin A.
    Samultsev, Dmitry O.
    Krivdin, Leonid B.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 123 (39): : 8417 - 8426
  • [27] THERMODYNAMIC CHARACTERISTICS OF THE ADSORPTION OF ORGANIC-SUBSTANCES ON THE IONIC ADSORBENT BARIUM-SULFATE WITH A MODIFIED SURFACE .2. ADSORPTION OF ALIPHATIC AND SOME HETEROCYCLIC NITROGEN-CONTAINING AND OXYGEN-CONTAINING-COMPOUNDS
    BELYAKOVA, LD
    LARIONOV, OG
    STROKINA, LM
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (11): : 2209 - 2214
  • [28] N-GLYCOSIDES OF NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS .2. STUDIES ON STRUCTURE OF 2-AMINO-5-(3-PYRIDYL)-1,3,4-OXADIAZOLE N-TETRA-O-ACETYL-D-GLUCOSIDE
    WIENIAWSKI, W
    WOJTOWICZ, M
    ACTA POLONIAE PHARMACEUTICA, 1974, 31 (03): : 287 - 291
  • [29] CRYSTAL STUDIES OF HETEROCYCLIC-COMPOUNDS CONTAINING ONE OXYGEN AND 2 NITROGEN-ATOMS .4. N,N'-DITOSYLPERHYDRO-1,4,6-OXADIAZOCINE
    DEREWENDA, U
    STEPIEN, A
    OLSZAK, TA
    KRAKOWIAK, K
    PERRIN, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2167 - 2169
  • [30] CRYSTAL STUDIES OF HETEROCYCLIC-COMPOUNDS CONTAINING ONE OXYGEN AND 2 NITROGEN-ATOMS .1. N,N'-DIBENZOYLPERHYDRO-1,4,5-OXADIAZEPINE
    STEPIEN, A
    WAJSMAN, E
    GRABOWSKI, MJ
    KRAKOWIAK, K
    PERRIN, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2162 - 2164
12345