The reagent Et2AlX/CH2N2 in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

被引：0
|
作者：
I. R. Ramazanov
A. V. Yaroslavova
N. R. Yaubasarov
E. N. Gil’manova
U. M. Dzhemilev
机构：
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源：
Russian Chemical Bulletin | 2019年 / 68卷
关键词：
organoaluminum compounds; diazomethane; aluminum carbenoids; cyclopropanation;
D O I：
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中图分类号：
学科分类号：
摘要：
A transition-metal-free method of cyclopropanation of sterically hindered olefins, substituted allylic alcohols, allylamines, and vinyl silyl ethers was developed using diazomethane in the presence of organic aluminum halides.
引用
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页码：1869 / 1873
页数：4
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