Synthesis, characterisation and thermal properties of [Cu(VO)2(C2O4)3(4,4′-bpy)2·2H2O]A 2D polymer

被引:0
|
作者
M. Vlad
I. Labádi
L. Saity
R. Tudose
W. Linert
O. Costisor
机构
[1] Institute of Chemistry Timisoara of Romanian Academy,Inorganic Chemistry Division
[2] University of Szeged,Department of Inorganic and Analytical Chemistry
[3] Vienna University of Technology,Institute of Applied Synthetic Chemistry
关键词
4,4′-bipyridine; copper; IR; oxalate ligand; thermal analysis; vanadium; UV-Vis;
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学科分类号
摘要
The heterometallic complex [Cu(VO)2(C10H8N2)2(C2O4)3·2H2O] has been prepared and characterised by electronic and IR spectra, molecular electrical conductivity and thermal behaviour. A polymeric structure is proposed with oxalate and 4,4′-dipyridine acting as bridging ligands and VO(IV) of C4v symmetry and Cu(II) in octahedral surrounding the oxalate anion V4h.
引用
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页码:925 / 928
页数:3
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