Synthesis, characterisation and thermal properties of [Cu(VO)2(C2O4)3(4,4′-bpy)2·2H2O]A 2D polymer

被引：0

作者：

M. Vlad

I. Labádi

L. Saity

R. Tudose

W. Linert

O. Costisor

机构：

[1] Institute of Chemistry Timisoara of Romanian Academy,Inorganic Chemistry Division

[2] University of Szeged,Department of Inorganic and Analytical Chemistry

[3] Vienna University of Technology,Institute of Applied Synthetic Chemistry

来源：

Journal of Thermal Analysis and Calorimetry | 2008年 / 91卷

关键词：

4,4′-bipyridine; copper; IR; oxalate ligand; thermal analysis; vanadium; UV-Vis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The heterometallic complex [Cu(VO)2(C10H8N2)2(C2O4)3·2H2O] has been prepared and characterised by electronic and IR spectra, molecular electrical conductivity and thermal behaviour. A polymeric structure is proposed with oxalate and 4,4′-dipyridine acting as bridging ligands and VO(IV) of C4v symmetry and Cu(II) in octahedral surrounding the oxalate anion V4h.

引用

页码：925 / 928

页数：3

共 50 条

[21] Thermogravimetric analysis of wheatleyite Na2Cu2+(C2O4)2·2H2O
R. L. Frost
A. Locke
W. N. Martens
Journal of Thermal Analysis and Calorimetry, 2008, 93
[22] Synthesis, structure and properties of a new copper (II) complex, [Cu2(4,4′-bpy)5(H2O)4](ClO4)4(4,4′-bpy)(DMF)2(H2O)2
Hu, Feilong
Yin, Xianhong
Mi, Yan
Li, Wanshu
Tang, Xinping
Ma, Zhen
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (06) : 720 - 723
[23] Thermogravimetric analysis of wheatleyite na2cu2+(c2o4)2•2h2o
Frost, R. L.
Locke, A.
Martens, W. N.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 93 (03) : 993 - 997
[24] Magnetic and catalytic properties of the 2D copper(II) functionalized VPO hybrid system [{Cu(bpy)}2(VO)3(PO4)2(HPO4)2]•2H2O
Venegas-Yazigi, D.
Munoz-Becerra, K.
Spodine, E.
Brown, K.
Aliaga, C.
Paredes-Garcia, V.
Aguirre, P.
Vega, A.
Cardoso-Gil, R.
Schnelle, W.
Kniep, R.
POLYHEDRON, 2010, 29 (12) : 2426 - 2434
[25] Crystal structure of (NH4)4[(UO2)2(C2O4)3(NCS)2] • 2H2O
Artem'eva, MY
Dolgushin, FM
Antipin, MY
Serezhkina, LB
Serezhkin, VN
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2004, 49 (03) : 369 - 372
[26] Syntheses and crystal structures of three novel oxalate coordination compounds: Rb2Co(C2O4) 2∼4H2O, Rb2CoCl2(C2O4) and K2Li2Cu(C2O4) 3∼2H2O
Clulow, Rebecca
Lightfoot, Philip
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 267 - +
[27] Synthesis,Crystal Structure and Characterization of the Coordination Polymer [Ni2（2-mpac）4（4,4'-bpy）·2H2O]n
范广
张引莉
孙家娟
徐维霞
郑敏燕
马占营
陈三平
高胜利
结构化学, 2010, 29 (08) : 1255 - 1259
[28] Speciation and transformation in the synthesis of Cu4(im)4(C4O3H6)2(NO2)4(H2O)4 and [(phen)Cu(C2O4)(H2O)]•H2O
Gong, Yun
Li, Hui
Li, Yang Guang
Wang, Yong Hui
Tang, Wang
Hu, Chang Wen
JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (01) : 61 - 71
[29] A 2-D copper coordination polymer [Cu(4,4'-bpy)(H2O)4] (C4H2O4)(H2O)4 integrated by hydrogen bonds and VDW interactions
Kang, Y
Li, ZH
Qin, YY
Chen, YB
Zhang, J
Hu, RF
Wen, YH
Cheng, HK
Yao, YG
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (08) : 862 - 864
[30] Synthesis, Crystal Structure and Characterization of the Coordination Polymer [Ni2(2-mpac)4(4,4′-bpy)•2H2O]n
Fan Guang
Zhang Yin-Li
Sun Jia-Juan
Xu Wei-Xia
Zheng Min-Yan
Ma Zhan-Ying
Chen San-Ping
Gao Sheng-Li
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (08) : 1255 - 1259

← 1 2 3 4 5 →