Adducts of zinc and copper(II) dialkyldithiocarbamate complexes with dibutyl-and diisobutylamines: Synthesis, structures, EPR and solid-state natural abundance 13C and 15N CP/MAS NMR spectra

被引：0
|
作者：
A. V. Ivanov
A. S. Zaeva
E. V. Novikova
A. V. Gerasimenko
W. Forsling
机构：
[1] Russian Academy of Sciences,Institute of Geology and Nature Management, Amur Scientific Center, Far East Division
[2] Blagoveshchensk State Pedagogical University,Institute of Chemistry, Far East Division
[3] Russian Academy of Sciences,undefined
[4] Luléa University of Technology,undefined
来源：
Russian Journal of Coordination Chemistry | 2007年 / 33卷
关键词：
Adduct; Tetragonal Pyramid; Dibutylamine; Zinc Diethyldithiocarbamate; Crystalline Adduct;
D O I：
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中图分类号：
学科分类号：
摘要：
Crystalline adducts of zinc and copper(II) dithiocarbamate complexes with dibutyl-and diisobutylamines of the general formula [M(NHR′2)(S2CNR2)2] (M = Zn, 63Cu, and 65Cu; R = CH3 and C2H5; R2 = (CH2)4O; R′ = C4H9 and i-C4H9) were synthesized. Their structures and spectroscopic properties were studied by EPR and solid-state natural abundance 13C and 15N CP/MAS NMR spectroscopy. Experimental EPR data and computer-assisted modeling confirmed the individual character of copper(II) adducts. The geometries of the copper coordination polyhedra were found to be intermediate between a tetragonal pyramid and a trigonal bipyramid (TBP). The contributions from TBP to the geometries of the adducts obtained were calculated from the EPR data. According to the X-ray diffraction data, the adduct of zinc diethyldithiocarbamate with diisobutylamine exists in two isomeric forms. The 13C and 15N CP/MAS NMR signals were assigned to the atomic positions in two crystallographically independent conformer molecules.
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页码：233 / 243
页数：10
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