Tetraphenyl- and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands:: Synthesis, X-ray diffraction analysis, and 13C and 15N CP/MAS NMR studies

被引：7
|
作者：
Sharutin, V. V.
Ivanov, M. A.
Gerasimenko, A. V.
Ivanov, A. V.
Pakusina, A. P.
Antsutkin, O. N.
Forsling, W.
Grobner, G.
机构：
[1] Blagoveshchensk State Pedag Univ, Blagoveshchensk 675000, Russia
[2] Russian Acad Sci, Inst Geol & Nat Management, Amur Sci Ctr, Far E Div, Blagoveshchensk, Russia
[3] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
[4] Lulea Univ Technol, S-97187 Lulea, Sweden
[5] Umea Univ, S-90187 Umea, Sweden
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 32卷 / 06期
关键词：
D O I：
10.1134/S1070328406060017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline tetraphenylantimony and tetratolylantimony complexes with N,N-dialkyldithiocarbamate ligands [Sb(C6H5)(4)(S2CNR2)] (R = CH3, C2H5, and C3H7 and R-2 = (CH2)(6)) were synthesized by ligand exchange reactions and studied by C-13 and N-15 CP/MAS NMR spectroscopy. X-ray diffraction analysis revealed that the complex [Sb(n-CH3-C6H4)(4){S2CN(C3H7)(2))] exists as the single molecular form, while [Sb(C6H5)(4){ S2CN(CH2)(6))] exists as two molecular conformers. The 13C and 15N signals were assigned to the C, positions of the atoms in the isomeric structures [Sb(C6H5)(4)[S2CN(CH2)(6)}] in terms of different degrees of double bonding in the formally single =N-C(S)S- bond.
引用
收藏
页码：387 / 396
页数：10
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