Kinetic model of the catalytic reaction of dimethylcarbonate with alcohols in the presence Co2(CO)8 and W(CO)6

被引：0

作者：

K. F. Koledina

S. N. Koledin

N. A. Schadneva

Y. Yu. Mayakova

I. M. Gubaydullin

机构：

[1] Institute of Petrochemistry and Catalysis of RAS,

[2] Ufa State Petroleum Technological University,undefined

来源：

Reaction Kinetics, Mechanisms and Catalysis | 2017年 / 121卷

关键词：

Green chemistry; Dimethyl carbonate; Kinetic model; Dicobaltoctacarbonyl; Tungsten hexacarbonyl;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A mathematical model of the reaction between dimethyl carbonate and alcohols in the presence of Co2(CO)8 and W(CO)6 has been developed. The proposed scheme for the reaction and kinetic models for each catalyst have been developed. A general scheme for the reaction between dimethyl carbonate and alcohols based on kinetic models has been developed. Active metal particles are formed from metal complex catalysts. These particles interact with dimethyl carbonate and run the catalytic cycle. Alkylmethyl ethers and alkylmethyl carbonates are the reaction products. The kinetic model shows the formation of ROCO2Me in the case of the catalyst Co2(CO)8, and ROMe is formed in the case of W(CO)6 as catalyst, which agrees with experimental data.

引用

页码：425 / 438

页数：13

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