Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

被引：0
|
作者：
Ivakhnenko, E. P. [1 ]
Vitkovskaya, Yu. G. [1 ]
Merezhko, N. I. [1 ]
Knyazev, P. A. [1 ]
Borodkin, G. S. [1 ]
Lysenko, K. A. [2 ]
Minkin, V. I. [1 ]
机构：
[1] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu, Russia
[2] Moscow MV Lomonosov State Univ, Moscow, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 03期
关键词：
redox-active ligands; indophenols; cadmium(II) complexes; tetranuclear cadmium(II) complexes; XRD;
D O I：
10.1134/S1070328423601309
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The.d(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L-1 and L-2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the H-1, C-13, and Cd-113 NMR spectroscopy (for complexes I and III) and IR spectroscopy data.
引用
收藏
页码：171 / 178
页数：8
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