Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures

被引：0

作者：

Ivakhnenko, E. P. ^{[1
]}

Vitkovskaya, Yu. G. ^{[1
]}

Merezhko, N. I. ^{[1
]}

Knyazev, P. A. ^{[1
]}

Borodkin, G. S. ^{[1
]}

Lysenko, K. A. ^{[2
]}

Minkin, V. I. ^{[1
]}

机构：

[1] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu, Russia

[2] Moscow MV Lomonosov State Univ, Moscow, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2024年 / 50卷 / 03期

关键词：

redox-active ligands; indophenols; cadmium(II) complexes; tetranuclear cadmium(II) complexes; XRD;

D O I：

10.1134/S1070328423601309

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The.d(II) complexes with redox amphoteric 2,6-di-(tert-butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L-1 and L-2 (adducts I, II, and III) are synthesized. The structures of coordinated complexes I, II, and III are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 1838319 (II) and 1838310 (III)) and confirmed by the H-1, C-13, and Cd-113 NMR spectroscopy (for complexes I and III) and IR spectroscopy data.

引用

页码：171 / 178

页数：8

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