Solvent-controlled self-assembly of tetrapodal [4 + 4] phosphate organic molecular cage

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作者：
Gen-Feng Feng
Jiao Geng
Fan-Da Feng
Wei Huang
机构：
[1] School of Chemistry and Chemical Engineering,State Key Laboratory of Coordination Chemistry
[2] Nanjing University,undefined
[3] Shenzhen Research Institute of Nanjing University,undefined
来源：
Scientific Reports | / 10卷
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摘要：
Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO2 adsorption over CH4 is demonstrated by the gas adsorption experiment.
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