Solvent-controlled self-assembly of tetrapodal [4+4] phosphate organic molecular cage

被引：7
|
作者：
Feng, Gen-Feng [1 ]
Geng, Jiao [1 ]
Feng, Fan-Da [1 ]
Huang, Wei [1 ,2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Shenzhen Res Inst, Shenzhen 518057, Guangdong, Peoples R China
来源：
SCIENTIFIC REPORTS | 2020年 / 10卷 / 01期
基金：
中国国家自然科学基金;
关键词：
PALLADIUM NANOPARTICLES EFFICIENT; HETEROGENEOUS CATALYSTS; SHAPE; ADSORPTION; CO2;
D O I：
10.1038/s41598-020-61813-6
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Two flexible subcomponents, namely tris(4-formylphenyl)phosphate and tris(2-aminoethyl)amine, are assembled into a tetrapodal [4 + 4] cage depending on the solvent effect. Single-crystal structure analysis reveals that the caivity is surrounded by four phosphate uints. Good selectivity of CO2 adsorption over CH4 is demonstrated by the gas adsorption experiment.
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页数：5
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