Self-Assembly of a Tetrapodal Adamantane with Carbazole Branches into Hollow Spherical Aggregates in Organic Media

被引：6

作者：

Tominaga, Masahide ^{[1
]}

Yoneta, Tetsuro ^{[1
]}

Ohara, Kazuaki ^{[1
]}

Yamaguchi, Kentaro ^{[1
]}

Itoh, Tsutomu ^{[2
]}

Minamoto, Chihiro ^{[3
]}

Azumaya, Isao ^{[4
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Sanuki, Kagawa 7692193, Japan

[2] Chiba Univ, Ctr Analyt Instrumentat, Inage Ku, Chiba 2638522, Japan

[3] Niihama Natl Coll Technol, Dept Appl Chem & Biotechnol, Niihama, Ehime 7928580, Japan

[4] Toho Univ, Fac Pharmaceut Sci, Chiba 2748510, Japan

来源：

ORGANIC LETTERS | 2014年 / 16卷 / 17期

关键词：

VESICLES; WATER; NANOCAPSULES; MACROCYCLES; NANOCAGES; SYSTEMS; TUBULES; DESIGN;

D O I：

10.1021/ol502116m

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A hydrophobic tetrapodal molecule is composed of carbazole units at the periphery linked by a phenyl spacer on an adamantane core. Tetrapodal adamantane self-assembles into hollow spherical aggregates with a multilayer membrane in organic media. The spherical assembly size is dependent on the organic solvent used. Hollow spheres can entrap guest molecules within their internal spaces. By increasing the concentrations of tetrapodal molecules, hollow spheres fused into necklace-shaped nanostructures and two-dimensional networks were obtained.

引用

页码：4622 / 4625

页数：4

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