Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+

被引：0

作者：

D. A. Loginov

M. M. Vinogradov

Z. A. Starikova

P. V. Petrovskii

J. Holub

A. R. Kudinov

机构：

[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds

[2] University of Pardubice,Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Research Centre for New Inorganic Compounds and Advanced Materials

来源：

Russian Chemical Bulletin | 2008年 / 57卷

关键词：

arene complexes; iron; metallacarboranes; sandwich compounds;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The benzene complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3a) was synthesized by the photochemical reaction of [(η5-C6H7)Fe(η-C6H6)]+ (1) with the anion [7-ButNH-7,8,9-C3B8H10]− followed by the treatment of ferracarborane 1-(η5-C6H7)-12-ButNH-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(η-C6R6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3b–e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction.

引用

页码：2294 / 2297

页数：3

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