Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+

被引：0
|
作者：
D. A. Loginov
M. M. Vinogradov
Z. A. Starikova
P. V. Petrovskii
J. Holub
A. R. Kudinov
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] University of Pardubice,Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Research Centre for New Inorganic Compounds and Advanced Materials
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
arene complexes; iron; metallacarboranes; sandwich compounds;
D O I：
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学科分类号：
摘要：
The benzene complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3a) was synthesized by the photochemical reaction of [(η5-C6H7)Fe(η-C6H6)]+ (1) with the anion [7-ButNH-7,8,9-C3B8H10]− followed by the treatment of ferracarborane 1-(η5-C6H7)-12-ButNH-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(η-C6R6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3b–e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction.
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页码：2294 / 2297
页数：3
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