Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+

被引：0
|
作者：
D. A. Loginov
M. M. Vinogradov
Z. A. Starikova
P. V. Petrovskii
J. Holub
A. R. Kudinov
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
[2] University of Pardubice,Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Research Centre for New Inorganic Compounds and Advanced Materials
来源：
Russian Chemical Bulletin | 2008年 / 57卷
关键词：
arene complexes; iron; metallacarboranes; sandwich compounds;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The benzene complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3a) was synthesized by the photochemical reaction of [(η5-C6H7)Fe(η-C6H6)]+ (1) with the anion [7-ButNH-7,8,9-C3B8H10]− followed by the treatment of ferracarborane 1-(η5-C6H7)-12-ButNH-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(η-C6R6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3b–e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction.
引用
收藏
页码：2294 / 2297
页数：3
相关论文
共 50 条
  • [1] Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+
    Loginov, D. A.
    Vinogradov, M. M.
    Starikova, Z. A.
    Petrovskii, P. V.
    Holub, J.
    Kudinova, A. R.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (11) : 2294 - 2297
  • [2] Photochemical arene exchange in the iron dicarbollide complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+
    D. A. Loginov
    M. M. Vinogradov
    Z. A. Starikova
    A. R. Kudinov
    Russian Chemical Bulletin, 2013, 62 : 1262 - 1267
  • [3] Photochemical arene exchange in the iron dicarbollide complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+
    Loginov, D. A.
    Vinogradov, M. M.
    Starikova, Z. A.
    Kudinov, A. R.
    RUSSIAN CHEMICAL BULLETIN, 2013, 62 (05) : 1262 - 1267
  • [4] Photochemical arene exchange in the naphthalene complex [CpRu(η6-C10H8)]+
    Karslyan, E. E.
    Perekalin, D. S.
    Petrovskii, P. V.
    Borisova, A. O.
    Kudinov, A. R.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (03) : 585 - 588
  • [5] Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4
    Loginov, Dmitry A.
    Pronin, Andrei A.
    Starikova, Zoya A.
    Petrovskii, Pavel V.
    Kudinov, Alexander R.
    MENDELEEV COMMUNICATIONS, 2010, 20 (05) : 271 - 272
  • [6] Photochemical arene exchange in the naphthalene complex [CpRu(η6-C 10H8)]+
    E. E. Karslyan
    D. S. Perekalin
    P. V. Petrovskii
    A. O. Borisova
    A. R. Kudinov
    Russian Chemical Bulletin, 2009, 58 : 585 - 588
  • [7] Benzene complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ as a synthon for the cationic ferracarborane moiety
    Loginov, D. A.
    Vinogradov, M. M.
    Shul'pina, L. S.
    Vologzhanina, A. V.
    Petrovskii, P. V.
    Kudinov, A. R.
    RUSSIAN CHEMICAL BULLETIN, 2007, 56 (10) : 2118 - 2120
  • [8] Benzene complex [(η-9-SMe2-7,8-C2B9H10)Fe(η-C6H6)]+ as a synthon for the cationic ferracarborane moiety
    D. A. Loginov
    M. M. Vinogradov
    L. S. Shul’pina
    A. V. Vologzhanina
    P. V. Petrovskii
    A. R. Kudinov
    Russian Chemical Bulletin, 2007, 56 : 2118 - 2120
  • [9] Thermal arene exchange in the naphthalene complex [CpRu(η6-C10H8)]+
    E. E. Karslyan
    D. S. Perekalin
    P. V. Petrovskii
    K. A. Lyssenko
    A. R. Kudinov
    Russian Chemical Bulletin, 2008, 57 : 2201 - 2203
  • [10] Thermal arene exchange in the naphthalene complex [CpRu(η6-C10H8)]+
    Karslyan, E. E.
    Perekalin, D. S.
    Petrovskii, P. V.
    Lyssenko, K. A.
    Kudinov, A. R.
    RUSSIAN CHEMICAL BULLETIN, 2008, 57 (10) : 2201 - 2203
12345