Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior

被引：0
|
作者：
Pavel A. Petrov
Elena A. Golubitskaya
Marsel R. Gallyamov
Aleksandra Yu. Andreeva
Taisiya S. Sukhikh
Maxim N. Sokolov
机构：
[1] Nikolaev Institute of Inorganic Chemistry SB RAS,
[2] Novosibirsk State University,undefined
[3] Kazan Federal University,undefined
来源：
Journal of Cluster Science | 2018年 / 29卷
关键词：
Molybdenum; Sulphur; Clusters; NMR;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two novel clusters [Mo3S4(dtc)3(μ-dtc)(L)] (where L = (CD3)2SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent 1H NMR spectroscopy, indicating order of lability tht ≫ py.
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页码：451 / 457
页数：6
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