Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior

被引：0
|
作者：
Pavel A. Petrov
Elena A. Golubitskaya
Marsel R. Gallyamov
Aleksandra Yu. Andreeva
Taisiya S. Sukhikh
Maxim N. Sokolov
机构：
[1] Nikolaev Institute of Inorganic Chemistry SB RAS,
[2] Novosibirsk State University,undefined
[3] Kazan Federal University,undefined
来源：
Journal of Cluster Science | 2018年 / 29卷
关键词：
Molybdenum; Sulphur; Clusters; NMR;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two novel clusters [Mo3S4(dtc)3(μ-dtc)(L)] (where L = (CD3)2SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent 1H NMR spectroscopy, indicating order of lability tht ≫ py.
引用
收藏
页码：451 / 457
页数：6
相关论文
共 50 条
  • [11] Synthesis and structure of raft-type molybdenum chalcogenide clusters
    Saito, T
    Imoto, H
    Tsuge, K
    Mita, S
    Mizutani, J
    Yamada, S
    Fujita, H
    TRANSITION METAL SULFUR CHEMISTRY: BIOLOGICAL AND INDUSTRIAL SIGNIFICANCE, 1996, 653 : 240 - 250
  • [12] SYNTHESIS AND CRYSTAL-STRUCTURES OF TRINUCLEAR MOLYBDENUM CHLORO SULFIDO CLUSTERS COORDINATED WITH TRIETHYLPHOSPHINE AND METHANOL
    SAITO, T
    YAMAMOTO, N
    YAMAGATA, T
    IMOTO, H
    CHEMISTRY LETTERS, 1987, (10) : 2025 - 2028
  • [13] Structure and behavior of serine clusters in solution and gas phase
    Costa, Anthony B.
    Nefliu, Marcela
    Perry, Richard H.
    Hall, Victoria J.
    Simpson, Garth J.
    Cooks, R. Graham
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [14] SYNTHESIS OF IRON MOLYBDENUM CLUSTERS
    LOPATIN, VE
    MIKOVA, NM
    GUBIN, SP
    KOORDINATSIONNAYA KHIMIYA, 1984, 10 (05): : 715 - 716
  • [15] ROTATION OF COORDINATED ACETYLIDE LIGANDS ON THE TRIANGULAR SURFACE OF TRINUCLEAR HETEROMETALLIC CLUSTERS
    HWANG, DK
    YUN, C
    PENG, SM
    LEE, GH
    ORGANOMETALLICS, 1990, 9 (10) : 2709 - 2718
  • [16] Supramolecular architectures built of triangular molybdenum(IV) heterometallic clusters encapsulating novel water clusters
    Dang, Zhen-Hua
    Zhao, Jun
    Xu, Li
    INORGANICA CHIMICA ACTA, 2009, 362 (09) : 2999 - 3004
  • [17] SYNTHESIS AND STRUCTURE OF A NOVEL POLYMOLYBDATE WHICH CONTAINS 5-COORDINATED MOLYBDENUM(VI)
    ICHIDA, H
    YAGASAKI, A
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (01) : 27 - 28
  • [18] SYNTHESES AND STRUCTURE OF CHLORIDE CLUSTERS OF MOLYBDENUM
    FEDIN, VP
    GERASCKO, OA
    FEDOROV, VE
    SLOVOKHOTOV, YL
    STRUCHKOV, YT
    IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK, 1988, (06): : 64 - 70
  • [19] Synthesis, Structure and Decarboxylative Behavior of a Nitro-coordinated Potassium Compound
    Li Dong-Mi
    Cui Jia-Jia
    Yao Jia-Xin
    Li Zhao-Hao
    Zhao Bang-Tun
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (03) : 362 - 368
  • [20] Synthesis, Structure and Decarboxylative Behavior of a Nitro-coordinated Potassium Compound
    李东密
    崔佳佳
    姚佳欣
    李召好
    赵邦屯
    Chinese Journal of Structural Chemistry, 2019, 38 (03) : 362 - 368
12345