Catalytic thiomethylation of regioisomeric aminobenzamides using bis(N,N-dimethylamino)methane and α,ω-alkanedithiols

被引:0
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作者
R. R. Khairullina
T. V. Tyumkina
A. G. Ibragimov
机构
[1] Russian Academy of Sciences,Institute of Petrochemistry and Catalysis
来源
Russian Chemical Bulletin | 2021年 / 70卷
关键词
thiomethylation; aminobenzamides; α,ω-alkanedithiols; bis-1,3-aminosulfides; bis(; -dimethylamino)methane; 3-(1,5,3-dithiazacycloalkan-3-yl)benzamides; 4-(1,5,3-dithiazacycloalkan-3-yl)benzamides; catalysis;
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摘要
A chemoselective synthesis of acyclic and cyclic S-containing aminobenzamides was developed. The method involved samarium-catalyzed thiomethylation of regioisomeric aminobenzamides at the amino group using either bis(N,N-dimethylamino)methane and α,ω-alkanedithiols or bis-1,3-aminosulfides.
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页码:757 / 762
页数:5
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