Catalytic thiomethylation of aminobenzamides using bis(N,N-dimethylamino)methane, hydrogen sulfide, and its sodium salts

被引:4
|
作者
Khairullina, R. R. [1 ]
Tyumkina, T., V [1 ]
Akhmetshina, G. A. [1 ]
Abdullin, M. F. [2 ]
Ibragimov, A. G. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa Fed Res Ctr, 141 Prosp Oktyabrya, Ufa 450075, Russia
[2] Russian Acad Sci, Ufa Inst Chem, Ufa Fed Res Ctr, 71 Prosp Oktyabrya, Ufa 450054, Russia
关键词
thiomethylation; aminobenzamides; bis(N; N-dtaeffiylarnrno)methane; formaldehyde; hydrogen sulfide; sodium sulfide nanohydrate; sodium hydrosulfide; N; S-heterocycles; catalysis; DERIVATIVES; 2-AMINOBENZAMIDE; INHIBITORS; AMINES;
D O I
10.1007/s11172-021-3070-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient method for the catalytic thiomethylation of regioisomeric aminobenzamides with bis(N,N-dimethylamino)methane (formaldehyde) and H2S (Na2S center dot 9H(2)O, NaHS) leading to acyclic S-containing aminobenzamide derivatives or N,S-heterocycles has been developed.
引用
收藏
页码:152 / 157
页数:6
相关论文
共 29 条
  • [1] Catalytic thiomethylation of aminobenzamides using bis(N,N-dimethylamino)methane, hydrogen sulfide, and its sodium salts
    R. R. Khairullina
    T. V. Tyumkina
    G. A. Akhmetshina
    M. F. Abdullin
    A. G. Ibragimov
    [J]. Russian Chemical Bulletin, 2021, 70 : 152 - 157
  • [2] Catalytic thiomethylation of regioisomeric aminobenzamides using bis(N,N-dimethylamino)methane and α,ω-alkanedithiols
    Khairullina, R. R.
    Tyumkina, T., V
    Ibragimov, A. G.
    [J]. RUSSIAN CHEMICAL BULLETIN, 2021, 70 (04) : 757 - 762
  • [3] Catalytic thiomethylation of regioisomeric aminobenzamides using bis(N,N-dimethylamino)methane and α,ω-alkanedithiols
    R. R. Khairullina
    T. V. Tyumkina
    A. G. Ibragimov
    [J]. Russian Chemical Bulletin, 2021, 70 : 757 - 762
  • [4] Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides
    Khairullina, R. R.
    Tyumkina, T. V.
    Geniyatova, A. R.
    Mullagil'dina, F. K.
    Ibragimov, A. G.
    [J]. RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2019, 89 (02) : 204 - 211
  • [5] Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides
    R. R. Khairullina
    T. V. Tyumkina
    A. R. Geniyatova
    F. K. Mullagil’dina
    A. G. Ibragimov
    [J]. Russian Journal of General Chemistry, 2019, 89 : 204 - 211
  • [6] Aminomethylation of chlorophyll a derivatives using bis(N,N-dimethylamino)methane
    Belykh, Dmitri V.
    Tarabukina, Irina S.
    Gruzdev, Ivan V.
    Kodess, Mikhail I.
    Kutchin, Aleksandr V.
    [J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2009, 13 (8-9) : 949 - 956
  • [7] Unexpected transformations of methylpheophorbide a under the action of bis(N,N-dimethylamino)methane
    Belykh, Dmitrii V.
    Tarabukina, Irina S.
    Gruzdev, Ivan V.
    Kutchin, Aleksandr V.
    [J]. MENDELEEV COMMUNICATIONS, 2007, 17 (06) : 340 - 342
  • [8] IR SPECTROSCOPIC PROPERTIES OF HYDROGEN-BONDING IN 1-1 SALTS OF 1,8-BIS(N,N-DIMETHYLAMINO)NAPHTHALENE
    GRECH, E
    MALARSKI, Z
    SOBCZYK, L
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1985, 129 (1-2) : 35 - 43
  • [9] HYDROGEN-SULFIDE SPLITTING OF N,N'-DIMETHYL BIS-SALTS OF THIOQUINANTHRENE AND ISOTHIOQUINANTHRENE
    MASLANKIEWICZ, A
    ZIEBA, A
    [J]. POLISH JOURNAL OF CHEMISTRY, 1994, 68 (01) : 93 - 98
  • [10] Nucleophilic displacement polymerization of N,N'-bis(p-chlorobenzylidine)-4,4'-diaminodiphenyl methane with sodium sulfide
    Mohanty, AK
    Misra, M
    Misra, B
    [J]. EUROPEAN POLYMER JOURNAL, 1997, 33 (07) : 1087 - 1091