Catalytic thiomethylation of aminobenzamides using bis(N,N-dimethylamino)methane, hydrogen sulfide, and its sodium salts

被引:4
|
作者
Khairullina, R. R. [1 ]
Tyumkina, T., V [1 ]
Akhmetshina, G. A. [1 ]
Abdullin, M. F. [2 ]
Ibragimov, A. G. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa Fed Res Ctr, 141 Prosp Oktyabrya, Ufa 450075, Russia
[2] Russian Acad Sci, Ufa Inst Chem, Ufa Fed Res Ctr, 71 Prosp Oktyabrya, Ufa 450054, Russia
关键词
thiomethylation; aminobenzamides; bis(N; N-dtaeffiylarnrno)methane; formaldehyde; hydrogen sulfide; sodium sulfide nanohydrate; sodium hydrosulfide; N; S-heterocycles; catalysis; DERIVATIVES; 2-AMINOBENZAMIDE; INHIBITORS; AMINES;
D O I
10.1007/s11172-021-3070-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient method for the catalytic thiomethylation of regioisomeric aminobenzamides with bis(N,N-dimethylamino)methane (formaldehyde) and H2S (Na2S center dot 9H(2)O, NaHS) leading to acyclic S-containing aminobenzamide derivatives or N,S-heterocycles has been developed.
引用
收藏
页码:152 / 157
页数:6
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共 29 条
  • [11] Hydrogen bonds in the adduct of 1,8-bis(N,N-dimethylamino)naphthalene (DMAN) with 4-(p-nitrophenyl)disic acid (NPDA)
    Grech, E
    Malarski, Z
    Milart, P
    Sawka-Dobrowolska, W
    Sobczyk, L
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 1997, 437 : 81 - 89
  • [12] SYNTHESIS OF BIS[N-(2-DEHYDRO-2-R-1-2-R-2-ACETYL)-4-(N,N-DIMETHYLAMINO)PYRIDINIUM]HYDROHALIDES VIA KETENE REACTION WITH ACYLONIUM SALTS
    LYASHCHUK, SN
    [J]. ZHURNAL ORGANICHESKOI KHIMII, 1993, 29 (02): : 413 - 414
  • [13] Reaction mechanism of nickel sulfide atomic layer deposition using bis(N,N′-di-tert-butylacetamidinato)nickel(ii) and hydrogen sulfide
    Zhang, Xu
    Zhou, Zhongchao
    Xu, Rui
    Guo, Jiayi
    Xu, Lina
    Ding, Yihong
    Xiao, Hongping
    Li, Xinhua
    Li, Aidong
    Fang, Guoyong
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (19) : 13465 - 13473
  • [14] A new reagent for nucleophilic aminomethylation: Doubly lithiated bis(dimethylamino)methane and its use for the synthesis of Si,N-heterocycles
    Karsch, HH
    [J]. CHEMISCHE BERICHTE, 1996, 129 (05) : 483 - 484
  • [15] Phase transfer catalytic reaction of n-bromobutane and sodium sulfide in a two-phase solution and its kinetics
    Wang, ML
    Tseng, YH
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) : 79 - 93
  • [16] Noncryogenic I/Br-Mg exchange of aromatic halides bearing sensitive functional groups using i-PrMgCl-bis[2-(N,N-dimethylamino)ethyl] ether complexes
    Wang, XJ
    Sun, XF
    Zhang, L
    Xu, YB
    Krishnamurthy, D
    Senanayake, CH
    [J]. ORGANIC LETTERS, 2006, 8 (02) : 305 - 307
  • [17] SOME C-13 AND N-15 NMR-STUDIES ON 1,8-BIS (DIMETHYLAMINO) NAPHTHALENE AND 2 OF ITS SALTS
    GRECH, E
    STEFANIAK, L
    ANDO, I
    YOSHIMIZU, H
    WEBB, GA
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (12) : 3761 - 3762
  • [18] Synthesis of 1,3-{Di-[N-bis(dimethylamino)methane]}-benzyl-diamide and its molecular recognition of nucleotides in aqueous solution
    Gao, HX
    Cai, LP
    Qi, YX
    Wang, HQ
    [J]. SUPRAMOLECULAR CHEMISTRY, 2003, 15 (05) : 323 - 325
  • [19] Study of Protein–Probe Interaction and Protective Action of Surfactant Sodium Dodecyl Sulphate in Urea-Denatured HSA using Charge Transfer Fluorescence Probe Methyl Ester of N,N-Dimethylamino Naphthyl Acrylic Acid
    Subrata Mahanta
    Rupashree Balia Singh
    Nikhil Guchhait
    [J]. Journal of Fluorescence, 2009, 19 : 291 - 302
  • [20] A MALDI-TOF MS analysis study of the binding of 4-(N, N-dimethylamino)pyridine to amine-bis(phenolate) chromium(III) chloride complexes: mechanistic insight into differences in catalytic activity for CO2/epoxide copolymerization
    Kozak, Christopher M.
    Woods, April M.
    Bottaro, Christina S.
    Devaine-Pressing, Katalin
    Ni, Kaijie
    [J]. FARADAY DISCUSSIONS, 2015, 183 : 31 - 46