Fluorescence studies on luminol in water-organic solvent mixtures

被引：0
|
作者：
Guha, D [1 ]
Das, R [1 ]
Mitra, S [1 ]
Mukherjee, S [1 ]
机构：
[1] INDIAN ASSOC CULTIVAT SCI,DEPT PHYS CHEM,CALCUTTA 700032,W BENGAL,INDIA
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1997年 / 36卷 / 04期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The spectral shift of fluorescence emission and photophysical propel-ties of luminol (3-aminophthalhydrazide) in various water/organic solvent mixtures have been studied using steady state and time resolved emission spectroscopy. The red shift in fluorescence spectra observed by the gradual addition of water in organic solvents containing luminol is interpreted as due to the stronger hydrogen bonding interaction between luminol and water molecules in the excited state. The fluorescence decay of luminol is described by biexponential kinetics in all the solvent mixtures. The origin of these biexponential decay kinetics has been interpreted as due to the formation of two different types of hydrogen bonded complexes between luminol/water and luminol/organic solvents. Fluorescence quenching of luminol by CCl4 and dilute triethylamine has also been examined.
引用
收藏
页码：307 / 312
页数：6
相关论文
共 50 条
  • [31] Ternary water-organic solvent mixtures used for insecticide SPE extraction and analysis with acetylcholinesterase biosensor
    Bucur, Madalina-Petruta
    Bucur, Bogdan
    Bacalum, Elena
    David, Victor
    Radu, Gabriel Lucian
    [J]. ANALYTICAL BIOCHEMISTRY, 2022, 654
  • [32] A method for calculation of solvent accessibility of aromatic amino acid residues of proteins in water-organic mixtures
    Shevchenko, AA
    Kost, OA
    [J]. BIOCHEMISTRY-MOSCOW, 1996, 61 (12) : 1502 - 1507
  • [33] Improvement of electrochemical biosensors using enzyme immobilization from water-organic mixtures with a high content of organic solvent
    Karyakin, AA
    Karyakina, EE
    Gorton, L
    Bobrova, OA
    Lukachova, LV
    Gladilin, AK
    Levashov, AV
    [J]. ANALYTICAL CHEMISTRY, 1996, 68 (24) : 4335 - 4341
  • [34] ACIDITY CONSTANTS OF ADENOSINE-5'-MONOPHOSPHATE AND DIPHOSPHATE IN VARIOUS WATER-ORGANIC SOLVENT MIXTURES
    AZAB, HA
    ELNADY, AM
    ELSHATOURY, SA
    [J]. MONATSHEFTE FUR CHEMIE, 1994, 125 (10): : 1049 - 1057
  • [35] FERRICINIUM ION AS OXIDIZING REAGENT IN CHEMILUMINESCENCE REACTION OF LUMINOL IN ORGANIC SOLVENT-WATER MIXTURES
    MATSUMOT.T
    SATO, M
    [J]. CHEMISTRY LETTERS, 1972, (10) : 869 - +
  • [36] Reactive dyeing of cotton in water-organic solvent mixture
    Lim, YJ
    Kim, TK
    Cho, KH
    [J]. SEN-I GAKKAISHI, 2001, 57 (01) : 21 - 24
  • [37] Stability of hydrolytic enzymes in water-organic solvent systems
    Simon, LM
    Laszlo, K
    Vertesi, A
    Bagi, K
    Szajani, B
    [J]. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 1998, 4 (1-2) : 41 - 45
  • [38] Photolysis of meta-azidophenol in water-organic mixtures
    Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia
    [J]. High Energy Chem., 4 (290-292):
  • [39] Photolysis of meta-azidophenol in water-organic mixtures
    L. N. Karyakina
    A. V. Oleinik
    Yu. V. Averyushina
    [J]. High Energy Chemistry, 2008, 42 : 290 - 292
  • [40] Photolysis of meta-azidophenol in water-organic mixtures
    Karyakina, L. N.
    Oleinik, A. V.
    Averyushina, Yu. V.
    [J]. HIGH ENERGY CHEMISTRY, 2008, 42 (04) : 290 - 292
12345