Oxidation of N-benzylaldimines to N-benzylamides by MCPBA and BF3•OEt2

被引：0
|
作者：
An, GI [1 ]
Rhee, H [1 ]
机构：
[1] Hanyang Univ, Dept Chem, Ansan 425791, Kyunggi Do, South Korea
来源：
SYNLETT | 2003年 / 06期
关键词：
N-benzylaldimines; aldehydes; peroxy intermediate; fragmentation; N-benzylamides;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N-Benzylamides were obtained from the corresponding N-benzylaldimines in high yields. N-Benzylaldimines are readily prepared from the corresponding aldehydes with benzylamine. This procedure involves the oxidation of N-benzylaldimines with MCPBA with BF3.OEt2. In this reaction, the reaction presumably follows an internal hydrogen abstraction to provide only N-benzylamide.
引用
收藏
页码：876 / 878
页数：3
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