Insertion of Ruthenium into an inorganic, cyclic biradicaloid

被引：0

作者：

Oswald, Jan ^{[1
]}

Scharnhoelz, Moritz T. ^{[1
]}

Coburger, Peter ^{[1
]}

Beer, Henrik ^{[2
]}

Bresien, Jonas ^{[2
]}

Schulz, Axel ^{[2
,3
]}

Gruetzmacher, Hansjoerg ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland

[2] Univ Rostock, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany

[3] Univ Rostock eV LIKAT, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 17期

基金：

瑞士国家科学基金会;

关键词：

Phosphorus heterocycles; Ruthenium; Metallacycles; Coordination chemistry; N; P ligands; 2,3-BIS(DIPHENYLPHOSPHINO)MALEIC ANHYDRIDE; COMPLEXES; MONONUCLEAR; LIGANDS;

D O I：

10.1002/zaac.202200093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Ru2Cl2(mu(2)-Cl)(2)(CO)(6)] and the biradicaloid [P(mu-NTer)](2) proceeds under insertion of a Ru(II)Cl(CO)(2) fragment into one P-N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X-ray analysis, NMR and IR spectroscopy and DFT calculations. The reactivity of the complex in a halide-pseudo-halide exchange reaction and a coordination reaction were investigated.

引用

页数：5

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