Insertion of Ruthenium into an inorganic, cyclic biradicaloid

被引：0

作者：

Oswald, Jan ^{[1
]}

Scharnhoelz, Moritz T. ^{[1
]}

Coburger, Peter ^{[1
]}

Beer, Henrik ^{[2
]}

Bresien, Jonas ^{[2
]}

Schulz, Axel ^{[2
,3
]}

Gruetzmacher, Hansjoerg ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland

[2] Univ Rostock, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany

[3] Univ Rostock eV LIKAT, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 17期

基金：

瑞士国家科学基金会;

关键词：

Phosphorus heterocycles; Ruthenium; Metallacycles; Coordination chemistry; N; P ligands; 2,3-BIS(DIPHENYLPHOSPHINO)MALEIC ANHYDRIDE; COMPLEXES; MONONUCLEAR; LIGANDS;

D O I：

10.1002/zaac.202200093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Ru2Cl2(mu(2)-Cl)(2)(CO)(6)] and the biradicaloid [P(mu-NTer)](2) proceeds under insertion of a Ru(II)Cl(CO)(2) fragment into one P-N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X-ray analysis, NMR and IR spectroscopy and DFT calculations. The reactivity of the complex in a halide-pseudo-halide exchange reaction and a coordination reaction were investigated.

引用

页数：5

共 50 条

[21] New cyclic ruthenium catalysts for olefin metathesis
不详
PRZEMYSL CHEMICZNY, 2019, 98 (12): : 1881 - 1881
[22] RUTHENIUM-CATALYZED CARBONYLATION OF CYCLIC AMINES
JENNER, G
BITSI, G
SCHLEIFFER, E
JOURNAL OF MOLECULAR CATALYSIS, 1987, 39 (02): : 233 - 236
[23] Polynuclear inorganic and organometallic complexes of ruthenium and their biological activity
Beckford, Floyd
Niece, Madison
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
[24] The velocity of hydrolysis of an inorganic salt, potassium ruthenium chloride
Lind, SC
Bliss, FW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1909, 31 : 868 - 885
[25] OXIDATION OF THIOLATO RUTHENIUM(III) COMPLEXES BY INORGANIC PEROXIDES
JOHNSON, MD
NICKERSON, D
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 66 - INOR
[26] REACTIONS OF CYCLIC DISULFIDES WITH CARBENES - DESULFURIZATION AND INSERTION
ANDO, W
KUMAMOTO, Y
TAKATA, T
TETRAHEDRON LETTERS, 1985, 26 (42) : 5187 - 5190
[27] Insertion of inorganic-biomolecular nanohybrid into eucaryotic cell
Kwak, SY
Hwang, SH
Jeong, YJ
Park, JS
Choy, JH
NANOPHASE AND NANOCOMPOSITE MATERIALS IV, 2002, 703 : 559 - 564
[28] Direct observation of a cationic ruthenium complex for ethylene insertion polymerization
Camacho-Fernandez, Miguel A.
Yen, Max
Ziller, Joseph W.
Guan, Zhibin
CHEMICAL SCIENCE, 2013, 4 (07) : 2902 - 2906
[29] INSERTION REACTIONS OF ACRYLONITRILE WITH HYDRIDOCARBONYLBIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CARBOXYLATES
DESHPANDE, SS
GOPINATHAN, S
GOPINATHAN, C
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 378 (01) : 103 - 107
[30] Nitrite linkage isomerization promoted by alkyne Insertion in ruthenium organometallics
Chattopadhyay, S
Ghosh, K
Pattanayak, S
Chakravorty, A
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2001, 40 (01): : 1 - 3

← 1 2 3 4 5 →