Insertion of Ruthenium into an inorganic, cyclic biradicaloid

被引：0

作者：

Oswald, Jan ^{[1
]}

Scharnhoelz, Moritz T. ^{[1
]}

Coburger, Peter ^{[1
]}

Beer, Henrik ^{[2
]}

Bresien, Jonas ^{[2
]}

Schulz, Axel ^{[2
,3
]}

Gruetzmacher, Hansjoerg ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland

[2] Univ Rostock, Inst Chem, Albert Einstein Str 3a, D-18059 Rostock, Germany

[3] Univ Rostock eV LIKAT, Leibniz Inst Katalyse, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 17期

基金：

瑞士国家科学基金会;

关键词：

Phosphorus heterocycles; Ruthenium; Metallacycles; Coordination chemistry; N; P ligands; 2,3-BIS(DIPHENYLPHOSPHINO)MALEIC ANHYDRIDE; COMPLEXES; MONONUCLEAR; LIGANDS;

D O I：

10.1002/zaac.202200093

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between [Ru2Cl2(mu(2)-Cl)(2)(CO)(6)] and the biradicaloid [P(mu-NTer)](2) proceeds under insertion of a Ru(II)Cl(CO)(2) fragment into one P-N bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X-ray analysis, NMR and IR spectroscopy and DFT calculations. The reactivity of the complex in a halide-pseudo-halide exchange reaction and a coordination reaction were investigated.

引用

页数：5

共 50 条

[1] ROUTES TO INORGANIC RUTHENIUM SULFIDES
KRAUTSCHEID, H
RAUCHFUSS, TB
SKAUGSET, AE
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 457 - INOR
[2] Fluorine insertion in inorganic materials
School of Chemistry, University of Birmingham, B15 2TT, Birmingham, United Kingdom
Current Opinion in Solid State and Materials Science, 1998, 3 (02): : 132 - 136
[3] Fluorine insertion in inorganic materials
Greaves, C
Francesconi, MG
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 1998, 3 (02): : 132 - 136
[4] Ruthenium complexes for olefin insertion polymerization
Friedberger, Tobias
Guan, Zhibin
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[5] Proton insertion in hydrous ruthenium oxides
Zheng, JP
Ma, ZR
Xin, Y
Fu, RQ
ELECTROCHEMICAL CAPACITOR AND HYBRID POWER SOURCES, 2002, 2002 (07): : 297 - 308
[6] PRESUPPOSITION IN CYCLIC LEXICAL INSERTION
MURAKI, M
FOUNDATIONS OF LANGUAGE, 1974, 11 (02): : 187 - 214
[7] Ruthenium-catalyzed decarboxylative insertion of electrophiles
Wang, C
Tunge, JA
ORGANIC LETTERS, 2005, 7 (11) : 2137 - 2139
[8] Ruthenium(IV) Complexes for Ethylene Insertion Polymerization
Friedberger, Tobias
Ziller, Joseph W.
Guan, Zhibin
ORGANOMETALLICS, 2014, 33 (08) : 1913 - 1916
[9] OXIDATION OF CYCLIC AMINES WITH RUTHENIUM TETROXIDE
SHEEHAN, JC
TULIS, RW
JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (15): : 2264 - 2267
[10] INSERTION REACTIONS OF ALKYLACETOXYSILANES WITH CYCLIC ETHERS
MEHROTRA, RC
BAJAJ, P
INDIAN JOURNAL OF CHEMISTRY, 1972, 10 (01): : 106 - &

← 1 2 3 4 5 →