Crystal and molecular structure of the yellow form of chloro(2,2′:6′,2′′-terpyridine) platinum (II)chloride dihydrate, [Pt(terpy)Cl]Cl•2H2O

被引：0
|
作者：
Sengül, A [1 ]
机构：
[1] Karaelmas Univ, Fac Arts & Sci, Dept Chem, Zonguldak, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2004年 / 28卷 / 05期
关键词：
X-ray structure; terpyridine; platinum; dimorph; complex;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis, characterization, and X-ray crystal structure of the yellow dimorph, [Pt(terpy)Cl]Cl(.)2H(2)O, are reported. The yellow acicular crystals are monoclinic: space group P2(1)/n, a = 6.908(3) Angstrom, b = 17.06700(11) Angstrom, c = 13.8390(10) Angstrom, beta = 98.607(4)degrees, and D-calc =2.204 Mg m(-3) for Z = 4. The cation consists of platinum coordinated to tridentate terpyridine ligand and to chloride ion. The coordination geometry is essentially square-planar with distortions arising from the constraints of the terpyridine ligand. Bond distances are within the acceptable limits of predicted values. The cations stack in a head-to-tail orientation with an intermolecular Pt-Pt distance of 3.39 Angstrom.
引用
收藏
页码：667 / 672
页数：6
相关论文
共 50 条
  • [31] Crystal and molecular of trans*-[Pt(Opro)2*(OH)2*]•2H2O and analysis of chiroptical properties of trans-[*-[Pt(Opro)2*X2*]•2H2O (X = OH, Cl)
    Minacheva, LK
    Sakharova, VG
    Kuznetsova, GN
    Golovaneva, IF
    Klyagina, AP
    ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (11): : 1827 - 1833
  • [32] Temperature dependence of the crystal structure and luminescence properties of [Pt{4′-(o-ClC6H4)trpy}Cl]SbF6 (trpy=2,2′:6′,2"-terpyridine)
    Field, JS
    Gertenbach, JA
    Haines, RJ
    Ledwaba, LP
    Mashapa, NT
    McMillin, DR
    Munro, OQ
    Summerton, GC
    DALTON TRANSACTIONS, 2003, (06) : 1176 - 1180
  • [33] Crystal structure of hexaaquanickel(II) perchlorate dihydrate, [Ni(H2O)6][ClO4]2•2H2O
    Staples, RJ
    Hatfield, TL
    Pierce, DT
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1998, 213 (02): : 243 - 244
  • [34] SYNTHESIS AND CHARACTERIZATION OF CYANATE-COPPER(II) COMPLEXES WITH 2,2' - 6',2''-TERPYRIDINE - CRYSTAL-STRUCTURE OF THE DIMERIC COMPOUND [CU(TERPY)(NCO)2]2-2H2O
    ROJO, T
    GARCIA, A
    MESA, JL
    ARRIORTUA, MI
    PIZARRO, JL
    FUERTES, A
    POLYHEDRON, 1989, 8 (01) : 97 - 102
  • [35] Crystal and molecular structure of diaquadinitratouranyl dihydrate [UO2(NO3)2(H2O)2] • 2H2O
    Sveshnikova, L. B.
    Mikhailov, Yu. N.
    Surazhskaya, M. D.
    Churakov, A. V.
    Belomestnykh, V. I.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2014, 59 (12) : 1430 - 1436
  • [36] Crystal and molecular structure of diaquadinitratouranyl dihydrate [UO2(NO3)2(H2O)2] · 2H2O
    L. B. Sveshnikova
    Yu. N. Mikhailov
    M. D. Surazhskaya
    A. V. Churakov
    V. I. Belomestnykh
    Russian Journal of Inorganic Chemistry, 2014, 59 : 1430 - 1436
  • [37] Synthesis and characterization of piperidine platinum(II) complexes with dicarboxylates:: crystal and molecular structure of cis-[ Pt(piperidine) 2Cl2]•H2O
    Khan, SRA
    Guzman-Jimenez, I
    Whitmire, KH
    Khokhar, AR
    POLYHEDRON, 2000, 19 (08) : 975 - 981
  • [38] CRYSTAL-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)MANGANESE(II) BIS(TRIIODIDE) [MN(TERPY)2](I3)2
    BHULA, R
    WEATHERBURN, DC
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1991, 44 (02) : 303 - 307
  • [39] Substitution of [Pt(terpy)H2O]2+ and [Pt(bpma)H2O]2+ with thiols in acidic aqueous solution.: terpy=2,2′:6′2"-terpyridine;: bpma = bis(2-pyridylmethyl)amine
    Jaganyi, D
    Tiba, F
    TRANSITION METAL CHEMISTRY, 2003, 28 (07) : 803 - 807
  • [40] The crystal structure of (2,2'-bipyridine)(pyrazine)(2,2':6',2''-terpyridine)ruthenium(II) hexafluorophosphate
    Gulyas, PT
    Hambley, TW
    Lay, PA
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1996, 49 (04) : 527 - 532
12345