CRYSTAL-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)MANGANESE(II) BIS(TRIIODIDE) [MN(TERPY)2](I3)2

被引：27
|
作者：
BHULA, R [1 ]
WEATHERBURN, DC [1 ]
机构：
[1] VICTORIA UNIV WELLINGTON, DEPT CHEM, POB 600, WELLINGTON, NEW ZEALAND
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1991年 / 44卷 / 02期
关键词：
D O I：
10.1071/CH9910303
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structue of [Mn(terpy)2](I3)2 terpy = 2,2':6', 2",-terpyridene) has been determined by X-ray crystallography. The crystals are triclinic, space group P1BAR, a 9.357(4), b 8.600(2), c 24.531(8) angstrom, alpha 93.64(2), beta 95.58(3), gamma 91.52(2)-degrees, Z 2, V 1960(1) angstrom-3. The structure has been refined to a residual R of 0.065 (R(w) 0.070). The coordination sphere of the metal ion is distorted octahedral with each terpy ligand coordinated in a meridional fashion. The structure is compared with those of other M(terpy)2n+ complexes formed by first-row transition metal ions.
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页码：303 / 307
页数：5
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