THE CRYSTAL-STRUCTURE OF BIS(2,2'/6',2TERPYRIDINE)NICKEL(II) PERCHLORATE HYDRATE

被引：37
|
作者：
BAKER, AT
CRAIG, DC
RAE, AD
机构：
[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA
[2] AUSTRALIAN NATL UNIV,RES SCH CHEM,CANBERRA,ACT 0200,AUSTRALIA
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 07期
关键词：
D O I：
10.1071/CH9951373
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of bis(2,2':6',2 ''-terpyridine)nickel(II) bis(perchlorate) hydrate has been determined by single-crystal X-ray diffractometry. The compound is monoclinic, space group P2(1), with two molecules in a unit cell of dimensions a 8.827(4), b 8.910(2), c 20.148(9) Angstrom, beta 98.71(2)degrees. The structure was refined by least-squares to a residual of 0.065 for 2184 observed reflections. The compound is found to be isomorphic with the iron(II) analogue previously reported: the cation has approximate D-2d symmetry, with the main distortion from octahedral symmetry being an axial compression. Both the solid state reflectance and solution spectra have been measured and some significant differences are noted.
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页码：1373 / 1378
页数：6
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