(9E)-9-Benzylidene-3-methyl-2-methylsulfanyl-5-phenyl-5,6,7,8,9,10-hexahydropyrimido[4,5-b]quinolin-4(3H)-one: polarized molecules within hydrogen-bonded bilayers

被引：2
|
作者：
Becerra, Diana [2 ]
Insuasty, Braulio [2 ]
Cobo, Justo [3 ]
Glidewell, Christopher [1 ]
机构：
[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[2] Univ Valle, Dept Quim, Cali 25360, Colombia
[3] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2010年 / 66卷
关键词：
CHAINS;
D O I：
10.1107/S0108270110023139
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecules of the title compound, C(26)H(25)N(3)OS, which was prepared by means of an acid-catalysed cyclocondensation reaction between a 6-aminopyrimidinone and 2,6-dibenzylidenecyclohexanone, exhibit a polarized electronic structure, namely (9E)-9-benzylidene-3-methyl-2-methylsulfanyl-5-phenyl-3,5,6,7,8,9-hexahydropyrimido[4,5-b]quinolin-10-ium-4-olate, involving charge separation in the vinylogous amide portion. Four hydrogen bonds, two each of the C-H...O and C-H...pi(arene) types, link the molecules into bilayers comprising inversion-related pairs of sheets, each containing a single type of R (4) 3(36) ring.
引用
收藏
页码：o389 / o391
页数：3
相关论文
共 50 条
  • [41] 1,9a-epoxy-1,2,3,4,4a,4b,5,8,8a,9a-decahydro-2-methyl-4-nitro-5,8-methano-9H-fluoren-9-one
    Fun, HK
    Chinnakali, K
    Hazra, NK
    Mal, D
    Nigam, GD
    Razak, IA
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1925 - 1927
  • [42] 10-(4-Fluorophenyl)-3,3,6,6,9-penta-methyl-3,4,6,7,9,10-hexahydro-acridine-1,8(2H,5H)-dione and 10-(4-fluorophenyl)-3,3,6,6-tetra-methyl-9-propyl-3,4,6,7,9,10-hexa-hydroacridine-1,8(2H,5H)-dione
    Pandi, AS
    Velmurugan, D
    Raj, SSS
    Fun, HK
    Seshadri, PR
    Thirumalai, D
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 : 821 - 824
  • [43] 2-(3,5-difluorophenoxy)-5-methyl-3-phenyl-8,9,10,11-tetrahydro-4H-benzo[4′,5′]thieno-[3′,2′:5,6]pyrido[4,3-d]pyrimidin-4(3H)-one
    Ren, Qing-Yun
    He, Hong-Wu
    Meng, Xiang-Gao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O5029 - O5031
  • [44] Crystal structure of (E)-2-benzylidene-4-[(3-phenyl-4,5-dihydroisoxazol-5-yl)-methyl]-2H-benzo[b][1,4] thiazin-3(4H)-one
    Sebbar, Nada Kheira
    Ellouz, Mohamed
    Essassi, El Mokhtar
    Saadi, Mohamed
    El Ammari, Lahccn
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O423 - U396
  • [45] Crystal structures of (3S,3aS,5aS,8S,9R,9aR,9bS)-3a,4,5,5a,6,7,8,9,9a,9b-decahydro-8-[2(2,6-dioxanyl)ethoxy]-3,5a,9-trimethyl-2(3H)-naphtho[1,2-b]- furanone (1) and (3S,3aS,5aS,8R,9R,9aR,9bS)-3a,4,5,5a,6,7,8,9,9a,9b-decahydro8-[2(2,6-dioxanyl)ethoxy]-3,5a,9-trimethyl-2(3H)-naphtho[1,2-b]furanone (2)
    Tanikawa, M
    Osa, Y
    Oshimoto, M
    Goto, S
    Takayanagi, H
    ANALYTICAL SCIENCES, 2002, 18 (09) : 1071 - 1072
  • [46] Crystal Structures of (3S,3aS,5aS,8S,9R,9aR,9bS)-3a,4,5,5a,6,7,8,9,9a,9b-Decahydro-8-[2(2,6-dioxanyl)ethoxy]-3,5a,9-trimethyl-2(3H)-naphtho[1,2-b]-furanone (1) and (3S,3aS,5aS,8R,9R,9aR,9bS)-3a,4,5,5a,6,7,8,9,9a,9b-Decahydro-8-[2(2,6-dioxanyl)ethoxy]-3,5a,9-trimethyl-2(3H)-naphtho[1,2-b]furanone (2)
    Miwako Tanikawa
    Yumiko Osa
    Masaomi Oshimoto
    Shino Goto
    Hiroaki Takayanagi
    Analytical Sciences, 2002, 18 : 1071 - 1072
  • [47] 2H,10H-1,4-dioxepino[5′,6′:4,5]thieno[3,2-e][1,4]dioxepine-5,7(3H,9H)-dione
    Tomura, Masaaki
    Ono, Katsuhiko
    Kaiden, Masanori
    Tsukamoto, Kenichi
    Saito, Katsuhiro
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4568 - U3757
  • [48] SYNTHESIS OF A NATURALLY-OCCURRING DIHYDROHOMOPTERIDINE INSECT METABOLITE, 6-ACETYL-2-AMINO-7,8-DIHYDRO-9H-PYRIMIDO[4,5-B][1,4]DIAZEPIN-4(3H)-ONE
    BOYLE, PH
    HUGHES, EM
    KHATTAB, HA
    LOCKHART, RJ
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1990, (07): : 2071 - 2077
  • [49] Crystal Structure of 3-methyl-1, 2, 3, 4, 4a, 4b, 9a, 15, 15a,15b-decahydro-（4,5）;（4a,15）-dimethano-tricyclo(4, 3, 1, 02,7) deca 〔8, 9, 1, 10-a, b, c〕pyrido〔4,3-a〕-acridin-6-en-9-ol-8-one
    HU Chun-Hua
    CHEN Jian
    ZHENG Pei-Ju(Research Center of Analysis and Measurement
    QIU Zhui-Bai
    YANG Jie(Department of Medicinal Chemistry
    结构化学, 1997, (03) : 186 - 190
  • [50] Theoretical study of isoelectronic molecules:: B6H10, 2-CB5H9, 2,3-C2B4H8, 2,3,4-C3B3H7, and 2,3,4,5-C4B2H6
    Tian, SX
    JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (29): : 6580 - 6586
12345