(9E)-9-Benzylidene-3-methyl-2-methylsulfanyl-5-phenyl-5,6,7,8,9,10-hexahydropyrimido[4,5-b]quinolin-4(3H)-one: polarized molecules within hydrogen-bonded bilayers

被引：2

作者：

Becerra, Diana ^{[2
]}

Insuasty, Braulio ^{[2
]}

Cobo, Justo ^{[3
]}

Glidewell, Christopher ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Valle, Dept Quim, Cali 25360, Colombia

[3] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2010年 / 66卷

关键词：

CHAINS;

D O I：

10.1107/S0108270110023139

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecules of the title compound, C(26)H(25)N(3)OS, which was prepared by means of an acid-catalysed cyclocondensation reaction between a 6-aminopyrimidinone and 2,6-dibenzylidenecyclohexanone, exhibit a polarized electronic structure, namely (9E)-9-benzylidene-3-methyl-2-methylsulfanyl-5-phenyl-3,5,6,7,8,9-hexahydropyrimido[4,5-b]quinolin-10-ium-4-olate, involving charge separation in the vinylogous amide portion. Four hydrogen bonds, two each of the C-H...O and C-H...pi(arene) types, link the molecules into bilayers comprising inversion-related pairs of sheets, each containing a single type of R (4) 3(36) ring.

引用

页码：o389 / o391

页数：3

共 50 条

[21] One-Pot Syntheses with 2-Substituted 6-Aminopyrimidin-4(3H)-ones: New 5-Aryl-5,8,9,10-tetrahydropyrimido[4,5-b]-quinoline-4,6(3H,7H)-diones and 5,5′-(Arylmethylene)-bis[6-amino-2-methylpyrimidin-4(3H)-ones]
Harutyunyan, A. A.
Israyelyan, S. G.
Panosyan, H. A.
Hakobyan, M. R.
Hovsepyan, T. R.
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 55 (12) : 1896 - 1901
[22] HETEROANALOGS OF ALLOXAZINES .3. REARRANGEMENTS OF 6,8-DIMETHYL-9A-HYDROXY-7,9-DIOXO-9AH-6,7,8,9-TETRAHYDRODIPYRIMIDO[4,5-B][4',5'-E]THIAZINES
SOLOVEVA, NP
ANISIMOVA, OS
SHEINKER, YN
NEMERYUK, MP
TRAVEN, NI
ARUTYUNYAN, TG
SHATUKHINA, EA
SAFONOVA, TS
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1992, (11): : 1576 - 1582
[23] 5-BENZYLIDENE-1,2,3,4,4A,5,6,7,8,9A-DECAHYDRO-4A-MORPHOLINO-9-PHENYLXANTHENE, C30H35NO2 (DBM), AND 5-BENZYLIDENE-1,2,3,4,4A,5,6,7,8,9A-DECAHYDRO-9-PHENYL-4A-PIPERIDINOXANTHENE, C31H37NO (DBP)
PONNUSWAMY, MN
TROTTER, J
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAR) : 511 - 514
[24] 2-Methoxy-4-(2-methoxyphenyl)-5,6,7,8,9,10-hexahydrocycloocta[b]pyridine-3-carbonitrile
Vishnupriya, R.
Suresh, J.
Maharani, S.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O656 - +
[25] 10-Benzyl-4-oxo-2,3,4,10-tetrahydropyrimido[4,5-b]quinolin-2-iminium chloride sesquihydrate: a polarized electronic structure within a complex hydrogen-bonded sheet structure
Trilleras, Jorge
Lopez, Luis G.
Cobo, Justo
Glidewell, Christopher
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2010, 66 : 469 - 472
[26] 3,3,6,6-Tetramethyl-9-phenyl-3,4,5,6-tetrahydro-9H-xanthene-1,8(2H,7H)-dione
Reddy, B. Palakshi
Vijayakumar, V.
Narasimhamurthy, T.
Suresh, J.
Lakshman, P. L. Nilantha
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O916 - U3344
[27] 3,4,6,7,9,10-hexahydro-3,3,6,6-tetramethyl-1,8(2H,5H)-dioxo-10-phenyl-9-acridinyl-methyl acetate
Gunasekaran, K
Velmurugan, D
Murugan, P
Ramakrishnan, VT
Panneerselvam, K
SorianoGarcia, M
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 2609 - 2612
[28] 1,9a-Epoxy-1,2,3,4,4a,4b,5,8,8a,9a-decahydro-2-methyl-4-nitro-5, 8-methano-9H-fluoren-9-one
Acta Crystallogr Sect C Cryst Struct Commun, pt 12 (1925-1927):
[29] Synthesis of 4-morpholino-5,8,9,10-tetrahydropyrimido[4,5-b]quinolin-6 (7H)-one derivatives and in silico-in vitro evaluation of their antimalarial activity
Patel, Pratik
Patel, Bhavin
Patel, Megha
Patel, Paresh
RESULTS IN CHEMISTRY, 2024, 7
[30] 9-METHYL-10-(4-METHYLPHENYL)-3,4,6,7,9,10-HEXAHYDRO-1,8(2H,5H)-ACRIDINEDIONE
SIVARAMAN, J
SUBRAMANIAN, K
VELMURUGAN, D
SUBRAMANIAN, E
RAMAKRISHNAN, VT
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1994, 50 : 2011 - 2013

← 1 2 3 4 5 →