Catalytic thiomethylation of regioisomeric aminobenzamides using bis(N,N-dimethylamino)methane and α,ω-alkanedithiols

被引：2

作者：

Khairullina, R. R. ^{[1
]}

Tyumkina, T., V ^{[1
]}

Ibragimov, A. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prosp Oktyabrya, Ufa 450075, Bashkortostan, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2021年 / 70卷 / 04期

关键词：

thiomethylation; aminobenzamides; alpha; omega-alkanedithiols; bis-1,3-aminosulfides; bis(N; N-dimethylamino)methane; 3-(1,5,3-dithiazacycloalkan-3-yl)benzamides; 4-(1,5,3-dithiazacycloalkan-3-yl)benzamides; catalysis; DERIVATIVES; POTENT; N; N-TETRAMETHYLMETHANEDIAMINE; 2-AMINOBENZAMIDE; INHIBITORS; ACTIVATOR;

D O I：

10.1007/s11172-021-3147-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chemoselective synthesis of acyclic and cyclic S-containing aminobenzamides was developed. The method involved samarium-catalyzed thiomethylation of regioisomeric aminobenzamides at the amino group using either bis(N,N-dimethylamino)methane and alpha,omega-alkanedithiols or bis-1,3-aminosulfides.

引用

页码：757 / 762

页数：6

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