Catalytic Cycloaminomethylation of Aminobenzamides with 1,3-Bis[dimethylamino(methoxy)methyl]thiourea

被引:3
|
作者
Khairullina, R. R. [1 ]
Tyumkina, T. V. [1 ]
Geniyatova, A. R. [1 ]
Abdullin, M. F. [2 ]
Ibragimov, A. G. [1 ]
机构
[1] Russian Acad Sci, Inst Petrochem & Catalysis, Pr Oktyabrya 141, Ufa 450075, Russia
[2] Russian Acad Sci, Ufa Inst Chem, Pr Oktyabrya 71, Ufa 450054, Russia
关键词
cycloaminomethylation; aminobenzamides; bis(N; N-dimethylamino)methane; thiourea; cyclophanes; DERIVATIVES; 2-AMINOBENZAMIDE; POTENT; AMINOMETHYLATION; CHEMISTRY; THIOUREAS;
D O I
10.1134/S1070363219030022
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficient methods of the synthesis of cyclophanes containing the thiourea moiety via the reaction of o-, m-, and p-aminobenzamides with 1,3-bis(dimethylaminomethyl)thiourea or 1,3-bis(methoxymethyl)thiourea using NiCl(2)6H(2)O and SmCl(3)6H(2)O as catalysts have been developed.
引用
收藏
页码:378 / 384
页数:7
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