Water-Stable Anionic Metal-Organic Framework for Highly Selective Separation of Methane from Natural Gas and Pyrolysis Gas

被引：144
|
作者：
Li, Lan [1 ,2 ]
Wang, Xusheng [2 ]
Liang, Jun [2 ]
Huang, Yuanbiao [2 ]
Li, Hongfang [2 ]
Lin, Zujin [2 ]
Cao, Rong [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 15期
关键词：
MOFs; phosphorus; light hydrocarbons; selectivity; water-stable; adsorption; CARBON-DIOXIDE CAPTURE; LIGHT-HYDROCARBONS; COORDINATION SITES; CO2; ADSORPTION; CONSTRUCTION; ACETYLENE; SORPTION; STORAGE; LIGAND; ENERGY;
D O I：
10.1021/acsami.6b00706
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A 3D water-stable anionic metal-organic framework [Zn-4(hpdia)(2)]center dot[NH2(CH3)(2)]center dot 3DMF center dot 4H(2)O (FJI-C4) was constructed based on an elaborate phosphorus-containing ligand 5,5'-(hydroxyphosphoryl)diisophthalic acid (H(5)hpdia). FJI-C4 with narrow one-dimensional (1D) pore channels exhibits high selectivity of C3H8/CH4 and C2H2/CH4. It is the first time for the MOF which contains phosphorus for selective separation of methane from natural gas and pyrolysis gas.
引用
收藏
页码：9777 / 9781
页数：5
相关论文
共 50 条
  • [41] Water-stable Metal-Organic Framework for Hyperpolarized Xenon MRI in Aqueous Solution
    Qingbin Zeng
    Zhen Wang
    Qianni Guo
    Wei Song
    Xiuchao Zhao
    Yuqi Yang
    Xin Zhou
    [J]. Chemical Research in Chinese Universities, 2025, 41 (2): : 305 - 312
  • [42] Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands
    张磊
    吴小园
    卢灿忠
    陈文哲
    [J]. Chinese Journal of Structural Chemistry, 2016, 35 (12) : 1929 - 1935
  • [43] A Water-Stable Cationic Metal-Organic Framework as a Dual Adsorbent of Oxoanion Pollutants
    Desai, Aamod V.
    Manna, Biplab
    Karmakar, Avishek
    Sahu, Amit
    Ghosh, Sujit K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (27) : 7811 - 7815
  • [44] Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands
    Zhang Lei
    Wu Xiao-Yuan
    Lu Can-Zhong
    Chen Wen-Zhe
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 35 (12) : 1929 - 1935
  • [45] Water-Stable Metal-Organic Framework/Polymer Composites Compatible with Human Hepatocytes
    Neufeld, Megan J.
    Ware, Brenton R.
    Lutzke, Alec
    Khetani, Salman R.
    Reynolds, Melissa M.
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (30) : 19343 - 19352
  • [46] Design and Synthesis of a Water-Stable Anionic Uranium-Based Metal-Organic Framework (MOF) with Ultra Large Pores
    Li, Peng
    Vermeulen, Nicolaas A.
    Gong, Xirui
    Malliakas, Christos D.
    Stoddart, J. Fraser
    Hupp, Joseph T.
    Farha, Omar K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (35) : 10358 - 10362
  • [47] Selective Adsorption-Based Separation of Flue Gas and Natural Gas in Zirconium Metal-Organic Frameworks Nanocrystals
    Li, Pengli
    Shen, Yongli
    Wang, Dandan
    Chen, Yanli
    Zhao, Yunfeng
    [J]. MOLECULES, 2019, 24 (09):
  • [48] Robust microporous hydrogen-bonded organic framework for highly selective purification of methane from natural gas
    Cai, Youlie
    Chen, Hongwei
    Liu, Puxu
    Chen, Jiazhen
    Xu, Hui
    Alshahrani, Thamraa
    Li, Libo
    Chen, Banglin
    Gao, Junkuo
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2023, 352
  • [49] Porous metal-organic framework materials for gas storage and separation
    Chen, Banglin
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [50] Metal-organic framework based membranes for gas separation processes
    Neves, L. A.
    Barreto, N.
    Crespo, J. C.
    Coelhoso, I. M.
    [J]. EUROMEMBRANE CONFERENCE 2012, 2012, 44 : 1991 - 1992
12345