A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides

被引：42
|
作者：
Hull, Jonathan F. [1 ]
Hilton, Sheena T. [1 ]
Crabtree, Robert H. [1 ]
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06511 USA
来源：
INORGANICA CHIMICA ACTA | 2010年 / 363卷 / 06期
关键词：
Beckmann rearrangement; Aldoxime; ONE-POT; ALDOXIMES; ALCOHOLS; REARRANGEMENT; HYDROGEN;
D O I：
10.1016/j.ica.2009.08.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ru(DMSO)(4)Cl-2 is catalytically active for converting aldehydes to primary amides via oxime intermediates. This catalyst is readily available, and requires no additional ligands, a great simplification compared to previous work. A Ru(II)/(IV) mechanism is proposed. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：1243 / 1245
页数：3
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