Terpyridine Ruthenium-Catalyzed One-Pot Conversion of Aldehydes into Amides

被引：104
|
作者：
Gnanamgari, Dinakar [1 ]
Crabtree, Robert H. [1 ]
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
来源：
ORGANOMETALLICS | 2009年 / 28卷 / 03期
关键词：
HIGHLY EFFICIENT; OXO COMPLEXES; ALDOXIMES; ALCOHOLS; OXIDATION; NITRILES; TRANSFORMATION; HYDROGEN; LIGANDS; CYCLOPROPANATION;
D O I：
10.1021/om8010678
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
TerpyRu(PPh3)Cl-2 is an efficient catalyst for rearranging aldoximes to amides without the need for chelating phosphines or additives as in prior examples. The catalyst is also useful in converting aldehydes into amides in a one-pot process using NaHCO3 as an additive. A mechanism involving nucleophilic attack of deprotonated oxime on an adjacent nitrile is suggested.
引用
收藏
页码：922 / 924
页数：3
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