Rhodium-Catalyzed Regio-, Diastereo-, and Enantioselective Three-Component Carboamination of Dienes via C-H Activation

被引：38

作者：

Mi, Ruijie ^{[1
]}

Zhang, Xuepeng ^{[1
]}

Wang, Jinlei ^{[1
]}

Chen, Haohua ^{[2
]}

Lan, Yu ^{[2
]}

Wang, Fen ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Peoples R China

[2] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China

来源：

ACS CATALYSIS | 2021年 / 11卷 / 11期

关键词：

enantioselective C-H activation; three-component; diene; allyl; amination; ALKENES; BONDS; ARYL;

D O I：

10.1021/acscatal.1c01615

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reported herein is the rhodium-catalyzed enantioselective three-component coupling of arene, diene, and dioxazolone that occurs via C-H activation en route to allyl intermediate. This carboamination reaction affords chiral allylic amines in 1,2-selectivity, E-selectivity, and enantioselectivity, with electrophilic amination of the pi-allyl species being both regio- and enantio-determining.

引用

页码：6692 / 6697

页数：6

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