Rhodium-Catalyzed Regio-, Diastereo-, and Enantioselective Three-Component Carboamination of Dienes via C-H Activation

被引：38
|
作者：
Mi, Ruijie [1 ]
Zhang, Xuepeng [1 ]
Wang, Jinlei [1 ]
Chen, Haohua [2 ]
Lan, Yu [2 ]
Wang, Fen [1 ]
Li, Xingwei [1 ]
机构：
[1] Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Peoples R China
[2] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China
来源：
ACS CATALYSIS | 2021年 / 11卷 / 11期
关键词：
enantioselective C-H activation; three-component; diene; allyl; amination; ALKENES; BONDS; ARYL;
D O I：
10.1021/acscatal.1c01615
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reported herein is the rhodium-catalyzed enantioselective three-component coupling of arene, diene, and dioxazolone that occurs via C-H activation en route to allyl intermediate. This carboamination reaction affords chiral allylic amines in 1,2-selectivity, E-selectivity, and enantioselectivity, with electrophilic amination of the pi-allyl species being both regio- and enantio-determining.
引用
收藏
页码：6692 / 6697
页数：6
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