Writing in a Polyaniline Film with Laser Beam and Stability of the Record: A Raman Spectroscopy Study

被引:43
|
作者
Moravkova, Zuzana [1 ]
Bober, Patrycja [1 ]
机构
[1] Czech Acad Sci, Inst Macromol Chem, Heyrovsky Sq 2, Prague, Czech Republic
关键词
CARBON NANOTUBES; IN-SITU; QUANTITATIVE CHARACTERIZATION; STRUCTURAL-CHANGES; ANILINE; POLYMERIZATION; NANOSTRUCTURES; CARBONIZATION; DEGRADATION; DISPERSION;
D O I
10.1155/2018/1797216
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Lines were drawn on polyaniline (PANI) salt films with laser beam, and then the samples were left to age in air at room temperature. Both the irradiated and intact parts of the sample and their ageing were studied with Raman spectroscopy. It was found that the laser-written record is reasonably stable. The degradation of polyaniline by laser irradiation and ageing was compared to the changes in PANI during heating. In all cases, deprotonation and crosslinking of PANI chains proceed but the relative rates of the processes vary with degradation conditions.
引用
收藏
页数:8
相关论文
共 50 条
  • [41] Polarized Raman spectroscopy study of NiSi film grown on Si(001) substrate
    Wan, Li
    Ren, Yiming
    Tang, Bo
    Cheng, Xinhong
    Zhang, Xuefei
    Xu, Dapeng
    Luo, Hijun
    Huang, Yunmi
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2009, 97 (03): : 693 - 697
  • [42] Surface enhanced Raman spectroscopy study of the galvanostatic reduction of the passive film on iron
    Dept. of Mat. Sci. and Mineral Eng., University of California, Berkeley, CA 94720, United States
    J Electrochem Soc, 11 (4061-4070):
  • [43] ELECTROCHEMICAL STUDY OF POLYANILINE FILM ELECTRODES AND THEIR MODIFICATIONS - IMPEDANCE SPECTROSCOPY MEASUREMENTS ON HYDROGEN EVOLUTION REACTION
    GRZESZCZUK, M
    ELECTROCHIMICA ACTA, 1994, 39 (11-12) : 1809 - 1816
  • [44] Characterization of substituted polyaniline films using Raman spectroscopy -: III.: Study of a methoxylated polymer:: POMA
    Bernard, M. C.
    Goff, A. Hugot-Le
    Arkoub, H.
    Saidani, B.
    ELECTROCHIMICA ACTA, 2007, 52 (15) : 5030 - 5038
  • [45] XRD and laser Raman spectroscopy investigation of the stability of low temperature t-ZrO2
    Stefanic, G
    Music, S
    Grzeta, B
    Popovic, S
    Sekulic, A
    CROATICA CHEMICA ACTA, 1998, 71 (03) : 789 - 806
  • [46] GE-SI ALLOY MICROSTRUCTURE FABRICATION BY DIRECT-LASER WRITING WITH ANALYSIS BY RAMAN MICROPROBE SPECTROSCOPY
    HERMAN, IP
    MAGNOTTA, F
    JOURNAL OF APPLIED PHYSICS, 1987, 61 (11) : 5118 - 5128
  • [47] Electrochemical impedance spectroscopy study of the passive film for laser-beam-melted 17-4PH stainless steel
    Barroux, A.
    Delgado, J.
    Orazem, M. E.
    Tribollet, B.
    Laffont, L.
    Blanc, C.
    CORROSION SCIENCE, 2021, 191
  • [48] Raman spectroscopy study of edible oils and determination of the oxidative stability at frying temperatures
    Carmona, Maria A.
    Lafont, Fernando
    Jimenez-Sanchidrian, Cesar
    Ruiz, Jose R.
    EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2014, 116 (11) : 1451 - 1456
  • [49] Structure and stability of p-cresol - xenon clathrate: Raman spectroscopy study
    Ilczyszyn, Maria M.
    Ilczyszyn, Marek
    Selent, Marcin
    JOURNAL OF MOLECULAR STRUCTURE, 2020, 1212
  • [50] PROBE BEAM HEATING OF ALGAAS SINGLE-QUANTUM-WELL LASER FACETS IN RAMAN MICROPROBE SPECTROSCOPY
    TANG, WC
    ROSEN, HJ
    BUCHMANN, P
    VETTIGER, P
    WEBB, D
    JOURNAL OF APPLIED PHYSICS, 1990, 68 (11) : 5930 - 5932