Structural exploration of hydroxo bridged triamine complexes of zinc(II)

被引：5

作者：

Mondal, A

Mostafa, G

Ghosh, A

Chaudhuri, NR ^{[1
]}

Wong, WT

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India

[2] Indian Assoc Cultivat Sci, Dept Solid State Phys, Xray Crystallog Lab, Calcutta 700032, W Bengal, India

[3] Bidhan Nagar Coll, Dept Chem, Calcutta 700064, W Bengal, India

[4] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong

来源：

POLYHEDRON | 1998年 / 17卷 / 08期

关键词：

hydroxo bridged zinc(II); triamine; zinc(II) triamine complex; single crystal structure;

D O I：

10.1016/S0277-5387(97)00404-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystal structure of [Zn-2(dpt)(2)(mu-OH)](ClO4)(3) (dpt = bis(3-aminopropyl) amine) shows that two units of Zn(dpt) are bridged by oxygen atom of the hydroxo group. Each Zn-atom possesses distorted tetrahedral geometry. Analogous complexes [Zn2L2(mu-OH)](ClO4)(3) [L = bis(3-aminopropyl) methylamine(medpt), bis (2-aminoethyl)methylamine(medien)] have been synthesised. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1217 / 1221

页数：5

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