Structural exploration of hydroxo bridged triamine complexes of zinc(II)

被引：5
|
作者：
Mondal, A
Mostafa, G
Ghosh, A
Chaudhuri, NR [1 ]
Wong, WT
机构：
[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Calcutta 700032, W Bengal, India
[2] Indian Assoc Cultivat Sci, Dept Solid State Phys, Xray Crystallog Lab, Calcutta 700032, W Bengal, India
[3] Bidhan Nagar Coll, Dept Chem, Calcutta 700064, W Bengal, India
[4] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong
来源：
POLYHEDRON | 1998年 / 17卷 / 08期
关键词：
hydroxo bridged zinc(II); triamine; zinc(II) triamine complex; single crystal structure;
D O I：
10.1016/S0277-5387(97)00404-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystal structure of [Zn-2(dpt)(2)(mu-OH)](ClO4)(3) (dpt = bis(3-aminopropyl) amine) shows that two units of Zn(dpt) are bridged by oxygen atom of the hydroxo group. Each Zn-atom possesses distorted tetrahedral geometry. Analogous complexes [Zn2L2(mu-OH)](ClO4)(3) [L = bis(3-aminopropyl) methylamine(medpt), bis (2-aminoethyl)methylamine(medien)] have been synthesised. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1217 / 1221
页数：5
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