Crystal structure, spectral and thermal properties of 2-aminopyridinium adipate monoadipic acid dihydrate

被引：36

作者：

Odabasoglu, M ^{[1
]}

Büyükgüngör, O

Turgut, G

Karadag, A

Bulak, E

Lönnecke, P

机构：

[1] Ondokuz Mayis Univ, Dept Chem, TR-55139 Samsun, Turkey

[2] Ondokuz Mayis Univ, Dept Phys, TR-55139 Samsun, Turkey

[3] Bogazici Univ, Dept Chem, TR-80815 Bebek, Turkey

[4] Univ Leipzig, Fak Chem & Mineral, Leipzig, Germany

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2003年 / 648卷 / 1-2期

关键词：

2-aminopyridinium adipate; 2-aminopyridinine; adipic acid; hydrogen bonding; X-ray crystal structure; IR; TG; DSC;

D O I：

10.1016/S0022-2860(02)00720-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In the title complex, C22H36N4O10, cyclic eight-membered hydrogen bonded rings exist involving 2-aminopyridinium and adipate ions. Adipic acid molecules and adipate ions are linked in zigzag chains by O-H...O hydrogen bonds. The characteristic IR absorption bands of 2-aminopyridinium adipate monoadipic acid dihydrate were observed as; 35002500 cm(-1) region (hydrogen bonded O-H and N-H stretch), 1695 cm(-1) (carboxylic C=O stretch), 1595 cm(-1) (C=N ring stretching and N-H bending vibrations), 1565 and 1395 cm(-1) (asymmetrical and symmetrical stretch of carboxylate ion, respectively). The title complex showed two thermal decomposition steps. Crystallization water release in the first step (105-118 degreesC) and remaining anhydrous complex decomposition completely in the second step (120-450 degreesC). (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：133 / 138

页数：6

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