Linear and nonlinear optical properties of 2-Aminopyridinium fumarate fumaric acid single crystal for optoelectronic device applications

被引:18
|
作者
Raju, E. [1 ,2 ]
Jayaprakash, P. [3 ]
Purushothaman, P. [1 ,2 ]
Vinitha, G. [4 ]
Devi, N. Saradha [5 ]
Kumaresan, S. [1 ]
机构
[1] Arignar Anna Govt Arts Coll, PG & Res Dept Phys, Cheyyar 604407, Tamil Nadu, India
[2] Thiruvalluvar Univ, Vellore 632115, Tamil Nadu, India
[3] St Josephs Inst Technol, Dept Phys, OMR, Chennai 600119, Tamil Nadu, India
[4] VIT Univ, Sch Adv Sci, Div Phys, Chennai 600127, Tamil Nadu, India
[5] Arignar Anna Govt Arts Coll, PG & Res Dept Chem, Cheyyar 604407, Tamil Nadu, India
关键词
2APFF; Crystal growth; 2-Aminopyridine; Fumaric acid; Thermal analysis; Dielectric studies; Nonlinear optical; GROWTH; NLO;
D O I
10.1016/j.cplett.2021.138941
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A good organic nonlinear optical single crystal of 2-Aminopyridine fumarate fumaric acid has been grown by slow evaporation technique. The analysis of single-crystal XRD demonstrates the centrosymmetric character of the grown crystal. The different functional groups and chemical composition are of 2APFF compounds were identified by using Fourier transform infrared spectral study. Spectral range of UV-vis-NIR studies shown that the transparency and band gap energy E-g = 6 eV of the grown crystal. Thermal property of 2APFF was analysed by differential scanning calorimetric technique. The mechanical properties 2APFF crystal was calculated for various load using the Vickers micro hardness tester. The dielectric behaviour of the grown crystal was studied for different temperatures at different frequencies. The third order NLO response in 2APFF was investigated using a Z-scan apparatus.
引用
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页数:7
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