Efficient Polymer Solar Cells Based on the Copolymers of Benzodithiophene and Thienopyrroledione

被引:334
|
作者
Zhang, Yong [1 ]
Hau, Steven K. [1 ]
Yip, Hin-Lap [1 ]
Sun, Ying [1 ]
Acton, Orb [1 ]
Jen, Alex K-Y. [1 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
基金
美国国家科学基金会;
关键词
BANDGAP;
D O I
10.1021/cm100417z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bulk heterojunction solar cells based on a novel low band gap polymer, PBDTTPD, were investigated. In the conventional device structures, a power conversion efficiency of 4.1% could be achieved from the thin film blend of PBDTTPD:PC71BM(1:2) with a current density of 9.8mAcm-2, Voc of 0.84 V, and FF of ∼ 50%. The high Voc (0.87 V) is the result of the lower HOMO level of the polymer. In addition, inverted devices with PBDTTPD: PC71BM (1:2) as active layer were also investigated. © 2010 American Chemical Society.
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页码:2696 / 2698
页数:3
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