Synthesis, structure, and magnetic properties of a cyclic dimer of bis(hexafluoroacetylacetonato)-{1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butyl-benzene}manganese(II)

被引：20
|
作者：
Gorlitz, G [1 ]
Hayamizu, T [1 ]
Itoh, T [1 ]
Matsuda, K [1 ]
Iwamura, H [1 ]
机构：
[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 08期
关键词：
D O I：
10.1021/ic971398b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cyclic dimer 1 was obtained by the reaction of the diradical 1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butylbenzene with Mn(hfac)(2). A spin transition occurs in 1 on cooling due to ferromagnetic coupling via the bidentate diradical ligand. The temperature dependence of the magnetic properties can be interpreted quantitatively in the frame of the HDvV formalism.
引用
收藏
页码：2083 / +
页数：4
相关论文
共 50 条
  • [41] Synthesis, Properties and Crystal Structure of Bis(tetra(n-butyl)ammonium) Bisnitrophthalocyaninatoruthenate(II)
    Sievertsen, Svend
    Weidemann, Morten
    Hueckstaedt, Heiner
    Homborg, Heiner
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 1997, 1 (04) : 379 - 384
  • [42] STRUCTURAL RESEARCHES ON COPPER(II) COMPLEXES WITH VITAMIN-B6 DERIVATIVES - X-RAY STRUCTURES OF BIS(N-TERT-BUTYL-PYRIDOXYLIDENEIMINATO)COPPER(II) AND BIS(N-TERT-BUTYL-PYRIDOXYLIDENEIMINATO)COPPER(II)-METHANOL (1-1/3)
    BIGOLI, F
    LANFRANCHI, M
    LEPORATI, E
    PELLINGHELLI, MA
    INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1983, 80 (03): : 135 - 143
  • [43] NCN Nickel(II) Pincer Complexes of 5-tert-Butyl-1,3-bis(N-substituted benzimidazol-2′-yl)benzenes: Solid and Solution State Behaviour
    Rani, Varsha
    Singh, Harkesh B.
    Butcher, Ray J.
    CHEMISTRYSELECT, 2018, 3 (42): : 11970 - 11976
  • [44] Synthesis and crystal structure of the copper(II) complex with N,N′-cyclohexanebis(3-formyl-5-tert-butyl-salicylaldimine)
    Liu, T
    Ruan, WJ
    Zhang, YL
    Zhu, ZA
    Chen, YT
    Heung, CH
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (03) : 199 - 202
  • [45] Crystal structure of 1,3-bis[N,N′-(3,5-di-tert-butyl)salicylideneimine]-2,2-dimethylpropane, C35H54O2N2
    Artus, GRJ
    Rauch, MU
    Herrmann, WA
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 1997, 212 (02): : 227 - 228
  • [46] Cationic NCN Palladium(ll) Pincer Complexes of 5-tert-Butyl-1,3-bis(N-substituted benzimidazol-2′-yl)benzenes: Synthesis, Structure, and Pd•••Pd Metallophilic Interaction
    Rani, Varsha
    Singh, Harkesh B.
    Butcher, Ray J.
    ORGANOMETALLICS, 2017, 36 (24) : 4741 - 4752
  • [47] Synthesis and characterization of 5-amino-1,3-di-tert-butyl-2H-tetrazol-1-ium bis[di-μ-chlorido-bis[dichloridocuprate(II)]]
    Voitekhovich, Sergei V.
    Lyakhov, Alexander S.
    Ivashkevich, Ludmila S.
    Schleife, Frederik
    Schnorr, Rene
    Kersting, Berthold
    Gaponik, Pavel N.
    INORGANICA CHIMICA ACTA, 2014, 419 : 124 - 129
  • [48] 1:1 Complexes of 5-(4-[N-tert-butyl-N-aminoxyl]phenyl) pyrimidine with manganese(II) and copper(II) hexafluoroacetonylacetonate
    Field, LM
    Lahti, PM
    Palacio, F
    CHEMICAL COMMUNICATIONS, 2002, (06) : 636 - 637
  • [49] Synthesis, structure and electrochemical properties of a cobalt(II) complex supported by 2-tetrahydrofurfurylamino-N,N-bis(2-methylene-4-tert-butyl-6-methyl)phenol
    Lin, Chen-Neng
    Zhou, Ling-Ling
    Fu, Ling-Zhi
    Zhan, Shu-Zhong
    Chen, Cai-Hong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 61 : 97 - 99
  • [50] Crystal structure and magnetic properties of the binuclear copper(II) complex based on 1,3-diaminopropan-2-ol N,N'-bis(3-formyl-5-tert-butylsalicylidene)
    Tupolova, Yu. P.
    Popov, L. D.
    Levchenkov, S. I.
    Shcherbakov, I. N.
    Suponitskii, K. Yu.
    Ionov, A. M.
    Kogan, V. A.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (07) : 552 - 555
12345