Synthesis, structure, and magnetic properties of a cyclic dimer of bis(hexafluoroacetylacetonato)-{1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butyl-benzene}manganese(II)

被引：20
|
作者：
Gorlitz, G [1 ]
Hayamizu, T [1 ]
Itoh, T [1 ]
Matsuda, K [1 ]
Iwamura, H [1 ]
机构：
[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan
来源：
INORGANIC CHEMISTRY | 1998年 / 37卷 / 08期
关键词：
D O I：
10.1021/ic971398b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The cyclic dimer 1 was obtained by the reaction of the diradical 1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butylbenzene with Mn(hfac)(2). A spin transition occurs in 1 on cooling due to ferromagnetic coupling via the bidentate diradical ligand. The temperature dependence of the magnetic properties can be interpreted quantitatively in the frame of the HDvV formalism.
引用
收藏
页码：2083 / +
页数：4
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