Reaction of benzyne with styrene oxide:: Insertion of arynes into a C-O bond of epoxides

被引：35
|
作者：
Beltran-Rodil, Sandra [1 ]
Pena, Diego [1 ]
Guitian, Enrique [1 ]
机构：
[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Organ, Santiago De Compostela 15782, Spain
来源：
SYNLETT | 2007年 / 08期
关键词：
arynes; epoxides; furans; insertions; ring expansion;
D O I：
10.1055/s-2007-977460
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Benzyne inserts into one of the C-O bonds of styrene oxide to form a dihydrobenzofuran as the major product together with five other reaction products. A detailed study of the reaction mixture clarified an intriguing forty-year-old personal communication from Stiles and Haag.
引用
收藏
页码：1308 / 1310
页数：3
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