Reaction of benzyne with styrene oxide:: Insertion of arynes into a C-O bond of epoxides

被引：35

作者：

Beltran-Rodil, Sandra ^{[1
]}

Pena, Diego ^{[1
]}

Guitian, Enrique ^{[1
]}

机构：

[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Organ, Santiago De Compostela 15782, Spain

来源：

SYNLETT | 2007年 / 08期

关键词：

arynes; epoxides; furans; insertions; ring expansion;

D O I：

10.1055/s-2007-977460

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzyne inserts into one of the C-O bonds of styrene oxide to form a dihydrobenzofuran as the major product together with five other reaction products. A detailed study of the reaction mixture clarified an intriguing forty-year-old personal communication from Stiles and Haag.

引用

页码：1308 / 1310

页数：3

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