N-Heterocyclic carbene stabilized Ag-P nanoclusters

被引：13

作者：

Najafabadi, Bahareh Khalili ^{[1
]}

Corrigan, John F. ^{[1
,2
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Univ Western Ontario, Ctr Adv Mat & Biomat Res, London, ON N6A 3K7, Canada

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

CHALCOGENIDE CLUSTERS; COPPER; SILVER; COMPLEXES; ROUTES;

D O I：

10.1039/c4cc06560c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The N-heterocyclic carbene (NHC) 1,3-di-isopropylbenzimidazole-2-ylidene (Pr-i(2)-bimy) is found to be an excellent ligand for the stabilization of silver-phosphorus polynuclear complexes. The straightforward preparation and characterization of the clusters [Ag-12(PSiMe3)(6)(Pr-i(2)-bimy)(6)] (1) and [Ag26P2(PSiMe3)(10)(Pr-i(2)-bimy)(8)] (2) are described, representing the first examples of such structurally characterized, higher nuclearity complexes obtained using this class of ligands.

引用

页码：665 / 667

页数：3

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