N-Heterocyclic carbene stabilized Ag-P nanoclusters

被引：13
|
作者：
Najafabadi, Bahareh Khalili [1 ]
Corrigan, John F. [1 ,2 ]
机构：
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
[2] Univ Western Ontario, Ctr Adv Mat & Biomat Res, London, ON N6A 3K7, Canada
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 04期
基金：
加拿大自然科学与工程研究理事会;
关键词：
CHALCOGENIDE CLUSTERS; COPPER; SILVER; COMPLEXES; ROUTES;
D O I：
10.1039/c4cc06560c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The N-heterocyclic carbene (NHC) 1,3-di-isopropylbenzimidazole-2-ylidene (Pr-i(2)-bimy) is found to be an excellent ligand for the stabilization of silver-phosphorus polynuclear complexes. The straightforward preparation and characterization of the clusters [Ag-12(PSiMe3)(6)(Pr-i(2)-bimy)(6)] (1) and [Ag26P2(PSiMe3)(10)(Pr-i(2)-bimy)(8)] (2) are described, representing the first examples of such structurally characterized, higher nuclearity complexes obtained using this class of ligands.
引用
收藏
页码：665 / 667
页数：3
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