Asymmetric autocatalysis

被引:0
|
作者
Chen Weifeng [1 ]
Shi Zhuangzhi [1 ]
Yuan Yu [1 ]
Yan Chaoguo [1 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China
关键词
asymmetric autocatalysis; enantioselectivity; chirality origin; nonlinear effects;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Asymmetric autocatalysis occurs when a chiral product operates as an asymmetric catalyst for its own production. Asymmetric autocatalysis intrinsically has the following advantages: chiral amplification of production, high reaction efficiency, easy purification of the products, consecutive reaction, which is a new aspect of chiral synthesis. Asymmetric autocatalysis combined with chirality amplification has been made the new concept in chirality origin. In the past decade the investigation and research on asymmetric autocatalysis have made great achievements. The recent advances in asymmetric autocatalysis are reviewed in this article.
引用
收藏
页码:456 / 463
页数:8
相关论文
共 67 条
  • [31] Ojima I., 2010, Catalytic Asymmetric Synthesis, V3rd
  • [32] New aspects of soai's asymmetric autocatalysis
    Podlech, J
    Gehring, T
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (36) : 5776 - 5777
  • [33] NONLINEAR EFFECTS IN ASYMMETRIC-SYNTHESIS - EXAMPLES IN ASYMMETRIC OXIDATIONS AND ALDOLIZATION REACTIONS
    PUCHOT, C
    SAMUEL, O
    DUNACH, E
    ZHAO, S
    AGAMI, C
    KAGAN, HB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) : 2353 - 2357
  • [34] Asymmetric synthesis utilizing circularly polarized light mediated by the photoequilibrium of chiral olefins in conjunction with asymmetric autocatalysis
    Sato, I
    Sugie, R
    Matsueda, Y
    Furumura, Y
    Soai, K
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (34) : 4490 - 4492
  • [35] Asymmetric autocatalysis initiated by chiral ephedrine immobilized on silica gel in a diisopropylzinc addition to pyrimidine-5-carbaldehyde
    Sato, I
    Shimizu, M
    Kawasaki, T
    Soai, K
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2004, 77 (08) : 1587 - 1588
  • [36] Enantioselective synthesis of substituted 3-quinolyl alkanols and their application to asymmetric autocatalysis
    Sato, I
    Nakao, T
    Sugie, R
    Kawasaki, T
    Soai, K
    [J]. SYNTHESIS-STUTTGART, 2004, (09): : 1419 - 1428
  • [37] Highly enantio selective asymmetric autocatalysis induced by chiral ionic crystals of sodium chlorate and sodium bromate
    Sato, I
    Kadowaki, K
    Ohgo, Y
    Soai, K
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 216 (02) : 209 - 214
  • [38] Highly enantioselective synthesis of organic compound using right- and left-handed helical silica
    Sato, I
    Kadowaki, K
    Urabe, H
    Jung, JH
    Ono, Y
    Shinkai, S
    Soai, K
    [J]. TETRAHEDRON LETTERS, 2003, 44 (04) : 721 - 724
  • [39] Asymmetric synthesis with a chiral catalyst generated from asymmetric autocatalysis
    Sato, I
    Urabe, H
    Ishii, S
    Tanji, S
    Soai, K
    [J]. ORGANIC LETTERS, 2001, 3 (24) : 3851 - 3854
  • [40] Amplification of chirality from extremely low to greater than 99.5 % ee by asymmetric autocatalysis
    Sato, I
    Urabe, H
    Ishiguro, S
    Shibata, T
    Soai, K
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (03) : 315 - +